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球磨-碱活化改性椰壳生物炭对恩诺沙星吸附性能

Modification of coconut shell biochar by ball milling with an alkali for enrofloxacin adsorption

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为了高效吸附水中的恩诺沙星(EFA),本文通过球磨法和KOH活化对椰壳进行改性制备椰壳生物炭(BM-KOH-BC),并在吸附EFA方面进行深入研究.通过扫描电子显微镜、傅里叶变换红外光谱和X射线衍射等方法对BM-KOH-BC进行表征,结果揭示了KOH活化和球磨改性显著提高了BM-KOH-BC的孔隙结构和比表面积.在优化条件下(初始EFA浓度为 80 mg·L-1 时,在pH值为 7,温度为 25℃,吸附剂剂量为0.14 g·mg·L-1,搅拌速度为 200 r/min、接触时间为 35 h的条件下,BM-KOH-BC表现出良好的吸附性能,去除率达77.4%,最大吸附容量为481.1 mg·g-1.吸附过程符合二级动力学模型和Freundlich等温线模型.此外,BM-KOH-BC在 5次吸附-解吸循环后仍保持高效的EFA去除率.这一低成本、高效吸附和可循环利用的特性使BM-KOH-BC在处理水体中的EFA方面展现出潜在的应用前景.
In order to efficiently adsorb enrofloxacin(EFA)in water,coconut shell biochar(BM-KOH-BC)was pre-pared by modifying coconut shell through ball milling and KOH activation,and in-depth research was conducted on the adsorption of EFA.BM-KOH-BC was characterized by scanning electron microscopy,Fourier transform infrared spectroscopy,and X-ray diffraction.The results revealed that KOH activation and ball milling modification significantly improved the pore structure and specific surface area of BM-KOH-BC.Under optimized conditions(Initial EFA concentration is 80 mg·L-1,pH value is 7,temperature is 25℃,adsorbent dosage is 0.14 g·mg·L-1,stirring speed is 200 r/min,contact time under the conditions of 35 h),BM-KOH-BC showed good adsorption per-formance,with a removal rate of 77.4%and a maximum adsorption capacity of 481.1 mg·g-1.The adsorption pro-cess is consistent with the second-order kinetic model and Freundlich isotherm model.In addition,BM-KOH-BC still maintains efficient EFA removal rate after 5 adsorption-desorption cycles.This low-cost,efficient adsorption and recyclability feature makes BM-KOH-BC show potential application prospects in treating EFA in water bodies.

ball-millingbiocharcoconut shellenrofloxacinadsorption

校导、郑丽丽、郑晓燕、杨旸、艾斌凌、盛占武

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中国热带农业科学院热带生物技术研究所,海口 571101

球磨 生物炭 椰壳 恩诺沙星 吸附

海南省重点研发计划海南省重点研发计划海南省自然科学基金中央级公益性科研院所基本科研业务费创新团队专项

ZDYF2023XDNY049ZDYF2019187319QN26717CXTD-05

2024

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

CSTPCD北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2024.41(8)