首页|TiC/Fe@氮掺杂碳纳米角复合材料的电磁吸波性能

TiC/Fe@氮掺杂碳纳米角复合材料的电磁吸波性能

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Fe/C复合材料因其优异的微波吸收性能而备受关注,但其阻抗匹配和匹配厚度有待进一步优化.本文通过高温等离子放电法在制备包覆Fe纳米颗粒的氮掺杂碳纳米角(Fe@NCNHs)的基础上引入了 TiC,成功合成包覆TiC和Fe纳米颗粒的氮掺杂碳纳米角(TiC/Fe@NCNHs)复合材料.这种复合材料具有良好的阻抗匹配,同时具备介电损耗、磁损耗、反射损耗等多种损耗机制,展现出良好的电磁波衰减性能.实验结果表明:当Fe和TiC纳米颗粒的负载量分别为9wt%和7wt%时,吸波性能最优.在频率为17.66 GHz处,其匹配厚度为1.4 mm,最小反射损耗达到-41.62 dB,有效吸收带宽为4.85 GHz(13.15~18 GHz).本文解决了Fe/C复合材料阻抗匹配差的问题,并且进一步优化了其电磁波衰减性能,获得了"薄、轻、宽、强"的TiC/Fe@NCNHs 吸波材料.
Electromagnetic absorption properties of TiC/Fe@nitrogen-doped carbon nanohorn composites
Fe/C composites have attracted much attention due to their excellent microwave absorption properties,but their impedance matching and matched thickness need to be further optimised.In this paper,TiC was intro-duced on the basis of the preparation of nitrogen-doped carbon nanohorns(Fe@NCNHs)encapsulating Fe nano-particles by high-temperature plasma discharge method,and N-doped carbon nanohorns(TiC/Fe@NCNHs)com-posites encapsulating TiC and Fe nanoparticles were successfully synthesised.This composite material has good impedance matching and various loss mechanisms such as dielectric loss,magnetic loss,reflection loss,etc.,and exhibits good electromagnetic wave attenuation performance.The experimental results show that the optimum wave-absorbing performance is achieved when the loadings of Fe and TiC nanoparticles are 9wt%and 7wt%,respectively.At a frequency of 17.66 GHz with a matched thickness of 1.4 mm,the minimum reflection loss reaches-41.62 dB and the effective absorption bandwidth is 4.85 GHz(13.15-18 GHz).In this study,the problem of poor im-pedance matching of Fe/C composites is solved,and the electromagnetic wave attenuation performance is further optimised,and the TiC/Fe@NCNHs wave-absorbing materials are obtained as"thin,light,wide and strong".

microwave absorptioncarbon nanohornTiCimpedance matchingreflection lossdielectric loss

许莉、朱启程、张育斌、南艳丽、乔明涛

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西安建筑科技大学 材料科学与工程学院,西安 710072

宁波财经学院,宁波 315175

微波吸收 碳纳米角 TiC 阻抗匹配 反射损耗 介电损耗

2025

复合材料学报
北京航空航天大学 中国复合材料学会

复合材料学报

北大核心
影响因子:0.933
ISSN:1000-3851
年,卷(期):2025.42(1)