非金属矿2024,Vol.47Issue(1) :99-102,107.

多元固废地聚合物的制备与性能研究

Preparation and Performance Study of Multi-Solid Waste Geopolymers

张延年 杨吴斌 韩东 回志峰 刘畅
非金属矿2024,Vol.47Issue(1) :99-102,107.

多元固废地聚合物的制备与性能研究

Preparation and Performance Study of Multi-Solid Waste Geopolymers

张延年 1杨吴斌 2韩东 3回志峰 3刘畅3
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作者信息

  • 1. 沈阳建筑大学 土木工程学院,辽宁 沈阳 110168;大连交通大学 土木工程学院,辽宁 大连 116028
  • 2. 沈阳建筑大学 土木工程学院,辽宁 沈阳 110168
  • 3. 辽宁省产品质量监督检验院,辽宁 沈阳 110031
  • 折叠

摘要

为实现尾矿等固废材料的再生利用,提高工业固废利用率,以铝土矿尾矿、矿渣和陶瓷粉为原料,NaOH-Na2SiO3 复合溶液为碱激发剂合成多元固废地聚合物,研究复合激发剂在不同碱当量时对地聚物抗压强度的影响,并通过X射线衍射(XRD)、傅里叶红外光谱(FTIR)和扫描电镜(SEM)探究影响机理.结果表明,随着复合激发剂碱当量的增加,地聚物各龄期抗压强度呈先增大后减小的趋势,当复合激发剂碱当量为5%时,制品28 d抗压强度达到最佳值,为63.3 MPa.适当增加碱当量对抗压强度有利,但碱当量过大会导致抗压强度降低.微观分析表明,不同碱当量合成的地聚物均发生了一定程度的聚合反应,并生成了以水化硅铝酸钙(C-A-S-H)为主的无定形水化产物,聚合反应程度随着碱当量的增加而增大,微观结构则表现为基体更均匀致密.

Abstract

In order to realize the recycling of tailing solid waste materials and improve the utilization rate of industrial solid waste,a multi-solid waste geopolymer was synthesized using bauxite tailings,glanulated blast furnace slag,and ceramic powder as raw materials,and NaOH-Na2SiO3 composite solution as an alkali activator.The effect of the composite activator on the compressive strength of the geopolymer at different alkali-equivalent was studied,and the influencing mechanism was explored through XRD,FTIR,and SEM.The results showed that with the increase of the alkali-equivalent of the composite activator,the compressive strength of the geopolymer at each age increased first and then decreased.When the alkali-equivalent of the composite activator was 5%,the compressive strength of the product at 28 d reached the optimal value of 63.3 MPa.Increasing the alkali-equivalent appropriately was beneficial for compressive strength,but excessive alkali-equivalent could lead to a decrease in compressive strength.Microscopic analysis showed that geopolymers synthesized with different alkali-equivalent had a certain degree of polymerization reaction and generated amorphous hydration products mainly composed of C-A-S-H.The degree of polymerization reaction increased with the increase of alkali-equivalent,and the microstructure showed that the matrix was more uniform and dense.

关键词

铝土矿尾矿/矿渣/陶瓷粉/地聚物/聚合反应/微观结构

Key words

bauxite tailings/glanulated blast furnace slag/ceramic powder/geopolymer/polymerization reaction/microstructure

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基金项目

国家自然科学基金重点项目(52234004)

沈阳市科技项目(22-322-3-04)

出版年

2024
非金属矿
苏州非金属矿工业设计研究院

非金属矿

CSTPCD
影响因子:0.636
ISSN:1000-8098
参考文献量7
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