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响应曲面法优化高硅铁尾矿制备硅肥试验

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为解决铁尾矿堆积造成的环境污染问题,以高硅铁尾矿为原料,在氢氧化钠、含钙活化剂SF混合碱液条件下进行水热-碱溶反应制作硅肥.采用 Box-Behnken设计的响应曲面法建立相关模型进行优化试验,探究反应温度(A)、反应时间(B)、m(SF)/m(原矿)(C)、m(NaOH)/m(SF)(D)对硅肥中有效硅含量的影响.结果表明,各因素对有效硅含量的显著作用大小为:B>D>A>C,各因素交互作用的显著性大小为:AD>CD>AC>BC.在温度为169.83℃、反应时间为2.54 h、m(SF)/m(原矿)为0.98、m(NaOH)/m(SF)为0.77的条件下,有效硅含量达到31.01%.该方法加工温度低、反应时间短、制备工艺简单,能够挖掘铁尾矿的潜在利用价值.
Optimization of Silicon Fertilizer Preparation from High Silicon Iron Tailings Using Response Surface Methodology
To solve the environmental pollution problem caused by the accumulation of iron tailings,silicon fertilizer was prepared from high silicon iron tailings by hydrothermal-alkali dissolution reaction under the conditions of alkaline mixture of sodium hydroxide and calcium containing activator SF.The response surface method designed by Box Behnken was used to establish a relevant model for optimization experiments.The effects of reaction temperature(A),reaction time(B),m(SF)/m(raw ore)(C),and m(NaOH)/m(SF)(D)on the effective silicon content in silicon fertilizer were investigated.The results showed that the significant effects of each factor on the effective silicon content were B>D>A>C,and the significance of interaction between each factor was AD>CD>AC>BC.Under the conditions of temperature of 169.83℃,reaction time of 2.54 h,m(SF)/m(raw ore)of 0.98,and m(NaOH)/m(SF)of 0.77,the effective silicon content reached 31.01%.This method has the advantages of low processing temperature,short reaction time,and simple preparation process,and can explore the potential utilization value of iron tailings.

iron tailingshydrothermal methodsilicon fertilizerhydrothermal-alkali dissolution technologyresponse surface method

牛福生、牛钰芳、张晋霞、张红梅、郑凯露

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华北理工大学 矿业工程学院,河北 唐山 063210

矿产资源绿色开发与生态修复协同创新中心,河北 唐山 063210

铁尾矿 水热法 硅肥 水热-碱溶技术 响应曲面法

2024

非金属矿
苏州非金属矿工业设计研究院

非金属矿

CSTPCD
影响因子:0.636
ISSN:1000-8098
年,卷(期):2024.47(1)
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