首页|三元固废掺和料耦合机理分析和活化

三元固废掺和料耦合机理分析和活化

扫码查看
为实现铁尾矿固废材料的再生利用,提高工业固废利用率,利用陶瓷粉和钢渣组成三元固废掺和料(铁尾矿-陶瓷粉-钢渣)并耦合活化.通过对铁尾矿进行不同时间的机械研磨,加入不同活化剂进行化学活化来提高铁尾矿的活性.采用差热-热重(DTA-TG)分析、扫描电镜(SEM)等方法研究三元掺和料的耦合活化和机械-化学活化机理.结果表明,适当增加铁尾矿研磨时间可以提升掺和料体系的活性指数,Na2SiO3 活化剂对掺和料体系活性提升最显著.在三元掺和料体系中,铁尾矿、陶瓷粉主要起填充作用,而钢渣中活性CaO、硅酸二钙(C2S)和硅酸三钙(C3S)成分可以参与水化反应生成较多水化产物,从而提升后期强度,复掺时活性指数均满足普通型Ⅱ级掺和料使用标准,最高活性指数可达88.29%,具备制备三元复合掺和料的潜力.
Coupling Activation Mechanism Analysis of Ternary Solid Waste Admixture
In order to realize the recycling and utilization of iron tailings solid waste and improve the utilization rate of industrial solid waste,a ternary solid waste admixture(iron tailings,ceramic powder and steel slag)was composed of ceramic powder and steel slag for coupling activation.The activity of iron tailings was improved by mechanical grinding at different times and chemical activation by adding different activators.The coupling activation and mechanical-chemical activation mechanism of ternary admixtures were studied by means of DTA-TG and SEM.The results showed that the activity index of the admixture system could be improved by appropriately increasing the grinding time of the iron tailings,and the active agent Na-2SiO3 was the most obvious factor for the activity deduction of the admixture system.In the ternary admixture system,iron tailings and ceramic powder mainly played the role of filling,while active CaO,C2S and C3S in the steel slag could participate in the hydration reaction to generate more hydration products and improve the late strength.The three materials had coupling effect,and the activity index met the standard of ordinary class Ⅱ admixture,and the highest activity index could reach 88.29%,which had the potential to prepare ternary composite admixture.

iron tailingsceramic powdersteel slagadmixturecoupling activationchemical activation

张延年、刘斌、刘柏男、韩东

展开 >

沈阳建筑大学 土木工程学院,辽宁 沈阳 110168

大连交通大学 土木工程学院,辽宁 大连 116028

东北大学 资源与土木工程学院,辽宁 沈阳 110819

辽宁省产品质量监督检察院,辽宁 沈阳 110031

展开 >

铁尾矿 陶瓷粉 钢渣 掺和料 耦合活化 化学活化

国家自然科学基金重点项目沈阳市科技计划

5223400422-322-3-04

2024

非金属矿
苏州非金属矿工业设计研究院

非金属矿

CSTPCD
影响因子:0.636
ISSN:1000-8098
年,卷(期):2024.47(2)
  • 9