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粒度对热改性煤矸石制备及吸附性能的影响

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以不同粒度煤矸石为原料制备热改性煤矸石,研究其对亚甲基蓝吸附性能的影响.结果表明,不同粒度热改性煤矸石最佳制备条件和最佳吸附条件均不相同.在750℃煅烧5 h的200目(74 μm)热改性煤矸石吸附效果最佳;在最佳吸附条件下,200目热改性煤矸石的最大吸附量为87 mg/g,比400目(37 μm)和600目(23 μm)热改性煤矸石分别高13%和9%.采用X射线衍射(XRD)仪、扫描电镜(SEM)和全自动比表面及孔隙度分析仪(BET)对样品进行表征,发现不同粒度热改性煤矸石较原煤矸石均变得疏松,但200目煤矸石效果更加显著,形成的孔隙主要是介孔.
Effect of Particle Size on Preparation and Adsorption Properties of Thermal Modified Coal Gangue
The coal gangue with different particle size was taken as raw material to prepare thermal modified coal gangue,and its effects on methylene blue adsorption were studied in this study.The results showed that the optimum preparation conditions and adsorption conditions of thermal modified coal gangue with different particle size were different.The thermal modified coal gangue with 200 mesh calcined at 750℃for 5 h achieved the best adsorption effect.Under the optimal adsorption conditions,the maximum adsorption capacity of modified coal gangue with 200 mesh was 87 mg/g,which were 13%and 9%higher than that of thermal modified coal gangue with 400 mesh and 600 mesh,respectively.XRD,SEM and BET were used to characterize the samples,and it was found that the thermal modified coal gangue with different particle size became porous compared with the original coal gangue,but coal gangue with 200 mesh had more significant effect,and the pores formed were mainly mesoporous.

thermal modified coal ganguemethylene blueadsorptionparticle size

魏瑞丽、赵俊丞、李育康、李泽文、刘德华、王瑞

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西安建筑科技大学华清学院,陕西 西安 710043

平泉冀东水泥有限责任公司,河北 承德 067500

热改性煤矸石 亚甲基蓝 吸附 粒度

陕西省教育厅专项科研计划项目2023年大学生创新创业训练计划项目

23JK0522S202313679015

2024

非金属矿
苏州非金属矿工业设计研究院

非金属矿

CSTPCD
影响因子:0.636
ISSN:1000-8098
年,卷(期):2024.47(4)
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