首页|(Cr,La)2(C,N)添加对Ti(C,N)基金属陶瓷结构与性能的影响

(Cr,La)2(C,N)添加对Ti(C,N)基金属陶瓷结构与性能的影响

扫码查看
在开放体系下采用高温碳管炉制备了(Cr,La)2(C,N)粉末,并将其作为添加剂制备Ti(C,N)基金属陶瓷。利用X射线衍射仪、扫描电镜、万能力学试验机及维氏硬度计等设备研究了(Cr,La)2(C,N)添加对Ti(C,N)基金属陶瓷微观组织和力学性能的影响。结果表明,(Cr,La)2(C,N)的添加能够有效细化Ti(C,N)基金属陶瓷的硬质相晶粒,其中Cr、La元素主要固溶于粘结相,La元素促进了硬质相的溶解-析出过程,金属陶瓷的抗弯强度、硬度以及断裂韧性等力学性能得到明显改善。当添加(Cr,La)2(C,N)的质量分数为5。0%时,Ti(C,N)基金属陶瓷的综合力学性能达到最佳,抗弯强度为2002 MPa,维氏硬度为1643 MPa,断裂韧性为11。22 MPa·m1/2。
Effect of(Cr,La)2(C,N)addition on the structure and properties of Ti(C,N)-based cermets
(Cr,La)2(C,N)powders were prepared by the high temperature carbon tube furnace in an open system,using as the additive to prepare the Ti(C,N)-based cermets.The effects of(Cr,La)2(C,N)on the microstructure and mechanical properties of the Ti(C,N)-based cermets were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),universal mechanical testing machine,and Vickers hardness tester.The results show that the addition of(Cr,La)2(C,N)can effectively refine the hard phase grains of the Ti(C,N)-based cermets.The Cr and La elements are mainly dissolved in the binder phase,and the La element promotes the dissolution and precipitation process of the hard phase.Furthermore,the bending strength,hardness,and fracture toughness of the cermets are significantly improved.When the mass fraction of(Cr,La)2(C,N)is 5.0%,the comprehensive mechanical properties of the Ti(C,N)-based cermets are the best,the bending strength is 2002 MPa,the Vickers hardness is 1643 MPa,and the fracture toughness is 11.22 MPa·m1/2.

Ti(C,N)-based cermets(Cr,La)2(C,N)microstructuremechanical propertiesfracture toughness

龙航飞、叶金文、曹之南

展开 >

四川大学材料科学与工程学院,成都 610064

Ti(C,N)基金属陶瓷 (Cr,La)2(C,N) 微观组织 力学性能 断裂韧性

四川省科技支撑"聚源兴川"项目

2023ZHJY0016

2024

粉末冶金技术
中国机械工程学会,中国金属学会,中国有色金属学会,北京科技大学

粉末冶金技术

CSTPCD北大核心
影响因子:0.341
ISSN:1001-3784
年,卷(期):2024.42(1)
  • 3