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类金刚石自润滑涂层对粉末冶金零件耐磨性的影响

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制备了不同密度的粉末冶金铁基零件,采用超声喷丸技术对粉末冶金样品进行表面致密化处理,选择不同密度的烧结态及喷丸处理粉末冶金样品作为基体,利用物理气相沉积技术在粉末冶金零件表面沉积了类金刚石自润滑涂层,研究类金刚石涂层的结合力与摩擦学性能。结果表明:密度高的基体与涂层结合力较好,经过喷丸强化处理的基体具有更好的结合力,约为28。0 N;但是在超声喷丸处理过程中,基体表层会产生巨大的压应力,基体与涂层内的残余应力累积会导致涂层过早失效;为减小超声喷丸带来的应力累积,对喷丸处理后的样品进行退火处理,退火后基体表面和涂层之间有更高的结合力,约 54。5 N。相比于裸基体,具有类金刚石涂层的样品摩擦性能大幅度提高,没有涂层保护的基体摩擦系数约为 0。60,具有类金刚石涂层保护的烧结态样品摩擦系数约为 0。15;与只做喷丸处理基体表面涂层的润滑性相比(摩擦系数 0。13~0。17),退火处理基体表面涂层的润滑性更稳定(摩擦系数约为0。13)。
Effect of diamond-like carbon self-lubricant coatings on wear resistance of powder metallurgy products
The iron-based parts with different densities were prepared by powder metallurgy,and then were densified by ultrasonic shot peening.The diamond-like carbon(DLC)self-lubricating coatings were deposited on the sintered and shot peening samples with different densities by physical vapor deposition,and the binding force and tribological properties of DLC coatings were studied.The results show that the matrix with high density has the better binding force with coatings,and the matrix treated with shot peening shows much better binding force,which is about 28.0 N.However,in the process of ultrasonic shot peening,the surface layers of the matrix produce huge compressive stress,and the accumulation of residual stress in the matrix and the coatings may lead to the premature failure of coatings.To reduce the stress accumulation caused by ultrasonic shot peening process,the samples are annealed after shot peening,and show much higher binding force between the matrix and coatings,about 54.5 N.The frictional properties of samples with DLC coating are greatly improved,the friction coefficient of the samples without coatings is about 0.60,and that of the sintered samples with DLC coatings is about 0.15.Compared with the DLC coatings on the matrix after shot peening(friction coefficient 0.13~0.17),the lubricity of DLC coatings on the annealed matrix is more stable(friction coefficient 0.13).

powder metallurgydiamond-like carbonself-lubricant coatingsultrasonic shot peeningannealwear resistance

朱烨彪、陈志东、郭武明、包崇玺

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东睦新材料集团股份有限公司,宁波 315191

中国科学院宁波材料技术与工程研究所,宁波 315201

粉末冶金 类金刚石 自润滑涂层 超声喷丸强化 退火 耐磨性

2024

粉末冶金技术
中国机械工程学会,中国金属学会,中国有色金属学会,北京科技大学

粉末冶金技术

CSTPCD北大核心
影响因子:0.341
ISSN:1001-3784
年,卷(期):2024.42(5)