首页|超临界水环境中应变速率对国产镍基合金应力腐蚀开裂敏感性的影响

超临界水环境中应变速率对国产镍基合金应力腐蚀开裂敏感性的影响

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采用慢应变速率试验(SSRT),研究了不同应变速率下国产镍基合金C-HRA-1在650℃、25 MPa超临界水环境中的应力腐蚀开裂(SCC)敏感性.采用扫描电子显微镜(SEM)观察了试样的断口形貌和表面裂纹形貌,采用能谱仪(EDS)分析了裂纹尖端附近的元素组成及分布.结果表明:在不同应变速率下,C-HRA-1均表现出SCC敏感性,随着应变速率的降低,SCC敏感性逐渐升高;在应力腐蚀过程中,裂纹的形成与扩展受氧化和力学耦合作用的影响,裂纹尖端发生了晶界氧化,裂尖结合力降低,从而导致裂纹扩展.
Effect of Strain Rate on Stress Corrosion Cracking Sensitivity of Domestic Nickel-Based Alloy in Supercritical Water Environment
The stress corrosion cracking(SCC)sensitivity of domestic nickel-based alloy C-HRA-1 in supercritical water environment of 650℃and 25 MPa at different strain rates was studied by slow strain rate test(SSRT).The fracture morphology and surface crack morphology of samples were observed by scanning electron microscope(SEM),and the element composition and distribution near the crack tip were analyzed by energy dispersive spectrometer(EDS).The results show that C-HRA-1 exhibited SCC sensitivity at different strain rates,and the SCC sensitivity increased with the decrease of strain rate.In the process of stress corrosion,the formation and propagation of cracks were affected by the coupling of oxidation and mechanics.The grain boundary oxidation occurred at the crack tip,which reduced the crack tip bonding force and led to crack propagation.

nickel-based alloystrain ratestress corrosion cracking(SCC)supercritical water

钟犁、刘学莹、马辰昊、徐鸿、张乃强、朱忠亮

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华北电力大学能源动力与机械工程学院,北京 102206

镍基合金 应变速率 应力腐蚀开裂(SCC) 超临界水

国家重点研发计划

2022YFB4100403

2024

腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCD北大核心
影响因子:0.462
ISSN:1005-748X
年,卷(期):2024.45(3)
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