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某硫冷凝器管束的腐蚀原因

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以某炼化公司4万t/a硫磺装置酸性气燃烧炉出口过程气一级冷凝冷却器的腐蚀为例,通过前期试漏试验、腐蚀减薄穿孔区域形貌观察、腐蚀产物化学成分分析、介质流态流速数值模拟等一系列方法评估了腐蚀原因.结果表明:该硫冷凝器管束发生腐蚀穿孔的主要原因是壳程介质没有提前除氧且pH控制不当导致的氧腐蚀和碱腐蚀,依据分析结果提出了相应的防腐蚀措施.
Corrosion Reason of a Sulfur Condenser Tube
Taking the corrosion of the first stage condensate cooler at the outlet of the acid gas combustion furnace in a 40 000 t/a sulfur refining company as an example,the corrosion cause was evaluated through a series of methods such as preliminary leak test,observation of the morphology of the corrosion thinning perforation area,analysis of the chemical composition of corrosion products,and numerical simulation of the flow rate of the medium.The results indicate that the main reason for the corrosion perforation of the sulfur condenser tube bundle was the oxygen corrosion and alkali corrosion caused by the shell side medium not being deoxidized in advance and improper pH control.Based on the analysis results,corresponding anti-corrosion measures were proposed.

failure analysissulfur condenseroxygen corrosionhydrodynamics simulationalkali corrosion

王奕璇、程学军、石李明、张宏飞、佘锋、包振宇、孙亮

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中石化炼化工程(集团)股份有限公司洛阳技术研发中心,洛阳 471032

中国石油化工股份有限公司安庆分公司,安庆 246000

中国石化工程建设有限公司,北京 100101

中海油惠州石化有限公司,惠州 516086

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失效分析 硫冷凝器 氧腐蚀 流体力学模拟 碱腐蚀

2024

腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCD北大核心
影响因子:0.462
ISSN:1005-748X
年,卷(期):2024.45(4)
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