首页|析出相及夹杂物对L80-9Cr钢耐蚀性的影响

析出相及夹杂物对L80-9Cr钢耐蚀性的影响

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通过电化学测试和FeCl3 点蚀试验,研究了Cr23C6 析出相及Al2O3 夹杂物对L80-9Cr钢耐蚀性的影响.结果表明:Cr23C6 在原马氏体板条束内的析出聚集增大了小角度晶界处的晶格畸变程度,使其具有较高的电化学活性,导致材料耐腐蚀性能降低;另一方面,Cr23C6 析出导致周围贫Cr区的形成,增大材料的点蚀倾向;此外,Al2O3 夹杂物的存在也为点蚀萌生与发展提供有利位置,两者的共同作用导致L80-9Cr钢的严重点蚀.
Effects of Precipitates and Inclusions on Corrosion Resistance of L80-9Cr Steel
The effects of Cr23C6 precipitates and Al2O3 inclusions on the corrosion resistance of L80-9Cr steel were studied by electrochemical test and FeCl3 pitting test.The results show that the precipitation and aggregation of Cr23C6 in the original martensitic lath bundles increased the degree of lattice distortion at the small-angle grain boundaries,making it have higher electrochemical activity and reducing the corrosion resistance of the material.On the other hand,the precipitation of Cr23C6 led to the formation of the surrounding Cr-depleted area,which increased the tendency of pitting corrosion of the material.In addition,the existence of Al2O3 inclusions also provided a favorable position for the initiation and development of pitting corrosion,and the combined effect of the two led to the severe pitting corrosion of L80-9Cr steel.

L80-9Cr steelAl2O3 inclusionCr-rich carbideFeCl3 pitting corrosionlattice distortion

卢道胜、陈宇凡、魏安超、董社霞、刘勇、杜宇峰、孙冲

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中海油田服务股份有限公司天津分公司,天津 300451

中国石油大学(华东)材料科学与工程学院,青岛 266580

中海油田服务股份有限公司海南分公司,海口 570312

L80-9Cr钢 Al2O3夹杂 富Cr碳化物 FeCl3点蚀 晶格畸变

中国海油石油集团有限公司-关键技术攻关项目中央高校基本科研业务费专项资金项目

CNOOC-KJGJHXJSGGYF2020-0120CX06075A

2024

腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCD北大核心
影响因子:0.462
ISSN:1005-748X
年,卷(期):2024.45(6)