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聚丙烯酸对蒸汽发生器二次侧泥渣颗粒的分散效果

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压水堆核电站蒸汽发生器(SG)二次侧泥渣颗粒主要成分为铁氧化物,采用静态沉降试验考察了分散剂聚丙烯酸(PAA)对Fe3O4和Fe2O3铁氧化物颗粒的分散效果.结果表明:PAA明显减缓了 Fe3O4和Fe2O3颗粒的沉降速率,其对前者的分散效果更优;PAA对颗粒的分散效果随着颗粒粒径的减小而增强,PAA对粒径在12 μm以下的Fe3O4颗粒具有明显的分散效果;PAA对铁氧化物颗粒保持较好分散效果的有效质量浓度范围较宽,在μg/L至mg/L级别;PAA对粒径小于28 µm的SG真实泥渣具有明显的分散效果,PAA的加入使得泥渣颗粒的悬浮率从34.05%提高至 56.93%.
Dispersion Effect of Polyacrylic Acid on Sludge Particles in the Secondary Side of Steam Generator
The main component of sludge particles in the secondary side of steam generator(SG)of PWR nuclear power plant was iron oxide.The dispersion effect of polyacrylic acid(PAA)on Fe3O4 and Fe2O3 iron oxide particles was investigated by static sedimentation tests.The results show that the sedimentation rate of Fe3O4 and Fe2O3 particles slowed down with PAA addition,and it showed better on Fe3O4 particles.The dispersion effect of PAA on iron oxide particles increased with the decrease of particle size,and PAA had obvious dispersion effect on Fe3O4 particles with particle size below 12 μm.The effective mass concentration of PAA to maintain high dispersing effect on iron-based particles was quite wide,ranging from μg/L to mg/L.PAA had obvious dispersing effect on SG real sludge in particle size less then 28 μm,and the addition of PAA improved its suspension efficiency from 34.05%to 56.93%.

polyacrylic acid(PAA)iron oxide particlestatic sedimentation testdispersion effectpressurized water reactor nuclear power plant

刘佳露、王骏、但体纯、杨顺龙、赖宏宇、邓清泉、吴申奥、操容、肖调兵、陈银强、桂春

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中核武汉核电运行技术股份有限公司,武汉 430223

福建福清核电有限公司,福州 350318

聚丙烯酸(PAA) 铁氧化物颗粒 静态沉降试验 分散效果 压水堆核电站

2024

腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCD北大核心
影响因子:0.462
ISSN:1005-748X
年,卷(期):2024.45(9)
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