腐蚀与防护2024,Vol.45Issue(10) :68-76.DOI:10.11973/fsyfh230498

温度和压力对密相CO2输送管线用X65钢腐蚀行为的影响

Effect of Temperature and Pressure on the Corrosion Behavior of X65 Pipeline Steel Used for Transporting Dense Phase CO2 Fluids

衣华磊 程璐瑶 胡丽华 李大朋 杨维健 孙冲 孙建波
腐蚀与防护2024,Vol.45Issue(10) :68-76.DOI:10.11973/fsyfh230498

温度和压力对密相CO2输送管线用X65钢腐蚀行为的影响

Effect of Temperature and Pressure on the Corrosion Behavior of X65 Pipeline Steel Used for Transporting Dense Phase CO2 Fluids

衣华磊 1程璐瑶 2胡丽华 1李大朋 1杨维健 2孙冲 2孙建波2
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作者信息

  • 1. 海洋油气高效开发全国重点实验室,北京 100028;中海油研究总院有限责任公司,北京 100028
  • 2. 中国石油大学(华东)材料科学与工程学院,青岛 266580
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摘要

通过腐蚀模拟试验、表面分析技术和水化学模拟计算等手段,研究了在低含水及含O2、H2S、SO2和NO2杂质的密相CO2腐蚀环境中X65管线钢的腐蚀行为,对比分析了温度和压力对X65钢腐蚀速率的影响及其原因.结果表明:温度和压力变化对X65钢的腐蚀速率影响显著,但不改变X65钢的腐蚀机理,X65钢表面形成了以FeOOH和FeSO4为主的腐蚀产物膜.在恒压密相CO2环境中,温度升高可以降低X65钢的腐蚀速率;而在恒温50 ℃密相CO2环境中,随压力升高腐蚀速率先降低后显著增加;在试验温度和压力范围内,X65钢在10 MPa和50 ℃的密相CO2环境中的腐蚀速率最低.温度和压力变化引起的X65钢腐蚀速率差异的原因与其造成的液相形成量及液相中腐蚀性物质含量的改变密切相关.

Abstract

The corrosion behavior of X65 pipeline steel in a dense phase CO2 corrosion environment with low water content and impurities such as O2,H2S,SO2,and NO2 was studied through corrosion simulation experiments,surface analysis techniques,and hydrochemical simulation calculations.The influence of temperature and pressure on the corrosion rate of X65 steel and reasons were compared and analyzed.The results show that the changes of temperature and pressure had a significant impact on the corrosion rate of X65 steel,but did not change the corrosion mechanism of X65 steel.A corrosion product film mainly composed of FeOOH and FeSO4 formed on the surface of X65 steel.In a dense CO2 environment with a constant pressure of 10 MPa,an increase in temperature could reduce the corrosion rate of X65 steel.In a dense CO2 environment at a constant temperature of 50 ℃,the corrosion rate first decreased and then significantly increased with increasing pressure.Within the experimental temperature and pressure range,X65 steel had the lowest corrosion rate in a dense CO2 environment at 10 MPa and 50 ℃.The reason for the difference in corrosion rate of X65 steel caused by temperature and pressure changes was closely related to the changes in the amount of liquid phase formation and the content of corrosive substances in the liquid phase.

关键词

X65管线钢/密相CO2/温度/压力/腐蚀

Key words

X65 pipeline steel/dense phase CO2/temperature/pressure/corrosion

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基金项目

中海油"十四五"重大科研项目(KJGG-2022-12-CCUS-0103)

中央高校基本科研业务费专项资金(20CX06075A)

出版年

2024
腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCDCSCD北大核心
影响因子:0.462
ISSN:1005-748X
参考文献量33
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