首页|橡胶混凝土的海洋微生物腐蚀行为

橡胶混凝土的海洋微生物腐蚀行为

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将橡胶粉代替部分河砂掺入混凝土中,可缓解当今废旧轮胎的黑色污染.以C40混凝土为基体,用橡胶粉代替等体积河砂,按3%、5%和10%的掺量配制橡胶混凝土,将橡胶混凝土分别置于天然海水和富含混合细菌的海水中腐蚀30 d后,通过直流电压加速渗透试验(RCM)和电化学测试,研究了微生物膜对氯离子渗透性的影响.结果表明:与未掺橡胶的C40混凝土相比,掺入5%橡胶骨料后,混凝土的抗压强度提高了12%,达到54.4 MPa,氯离子扩散系数降低了24.13%,C40混凝土在天然海水中的抗氯离子渗透性也得到提高;经微生物腐蚀后,材料表面附着的生物膜呈半透明龟裂状态,膜上分布多形态细菌群落,这种非均质破裂的生物膜未能起到保护作用,细菌的代谢作用大幅降低了橡胶混凝土的极化电阻Rct和阻抗模值|Zw|,加速了氯离子扩散进程.
Marine Microbial Corrosion Behavior of Rubber Concrete
Adding rubber powder instead of part of river sand into concrete can alleviate the black pollution of today's waste tires.With C40 concrete as the matrix,rubber powder was used to replace the equal volume of river sand,and rubber concrete was prepared with 3%,5%and 10%dosage.The rubber concrete was corroded in natural seawater and seawater rich in mixed bacteria for 30 days.The effect of microbial membrane on chloride ion permeability was studied by DC voltage accelerated permeability test(RCM)and electrochemical test.The results showed that compared with C40 concrete without rubber,the compressive strength of concrete with 5%rubber aggregate increased by 12%to 54.4 MPa,and the chloride ion diffusion coefficient decreased by 24.13%,which effectively improved the resistance of C40 concrete to chloride ion permeability in natural seawater.After microbial corrosion,the biofilm attached to the surface of the material was semi-transparent and cracked,and the polymorphic bacterial community was distributed on the membrane.This heterogeneous ruptured biofilm failed to play a protective role.The metabolic effect of bacteria greatly reduced the polarization resistance Rct and impedance modulus|Zw|of rubber concrete,and accelerated the diffusion process of chloride ions.

rubber concretemicrobial corrosionchloride ion diffusionelectrochemical impedance spectroscopy(EIS)

陈海燕、潘子烨、潘美诗、陈丕茂、余景、赵敏

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广东工业大学材料与能源学院,广州 510006

华南理工大学建筑学院,广州 510630

中国水产科学研究院南海水产研究所农业部南海渔业资源环境科学观测实验站,广州 510300

橡胶混凝土 微生物腐蚀 氯离子扩散 电化学阻抗谱(EIS)

2024

腐蚀与防护
上海市腐蚀科学技术学会 上海材料研究所

腐蚀与防护

CSTPCD北大核心
影响因子:0.462
ISSN:1005-748X
年,卷(期):2024.45(12)