首页|聚四氟乙烯固体自由基剂量计性能的研究

聚四氟乙烯固体自由基剂量计性能的研究

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聚四氟乙烯(PTFE)经电离辐射诱发能产生稳定自由基,本研究利用这一特点制备了一种PTFE固体剂量计片.实验数据和分析结果表明,该剂量计在较大剂量范围内(1~180 kGy)其自由基响应与吸收剂量保持正相关性,且受剂量率和能量依赖性的影响微小,同时辐照温度和辐照后存贮时间对PTFE固体剂量计片自由基衰退的影响呈现规律性.不同于目前行业使用的其他剂量计,该剂量计适用于高剂量范围测量与标定,量程范围在1~180 kGy,总不确定度小于5.02%,呈现优异的计量学性能.该研究对辐照加工聚合物材料或其他功能材料时的剂量精准调节和标定具有重要意义.
Investigating the performance of polytetrafluoroethylene solid free radical dosimeter
This study leverages the ability of polytetrafluoroethylene(PTFE)to generate stable free radicals under ionizing radiation to develop a solid PTFE dosimeter sheet.Experimental results indicate a strong positive correlation between free radical response and absorbed dose over a broad range(1‒180 kGy).The performance of the dosimeter was minimally influenced by dose rate and energy dependence,while the effects of irradiation temperature and post-irradiation storage time on free-radical decay exhibited clear and consistent patterns.Unlike conventional dosimeters used in the industry,the PTFE dosimeter is suitable for high-dose measurements and calibrations,covering a range of 1‒180 kGy with a total uncertainty of less than 5.02%,demonstrating high metrological reliability.This study provides valuable insights into precise dose control and calibration in the irradiation processing of polymers and other functional materials.

Ionizing radiationPTFE solid dosimeterFree radicalsHigh-dose rangeMetrological performance

常靖峰、张光华、吴国忠、沈蓉芳、董凯丰、郑康海

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上海金鹏源辐照技术有限公司 上海 201707

中国科学院上海应用物理研究所 上海 201800

电离辐射 PTFE固体剂量计 自由基 高剂量范围 计量学性能

2024

辐射研究与辐射工艺学报
中国科学院上海应用物理研究所

辐射研究与辐射工艺学报

CSTPCD
影响因子:0.527
ISSN:1000-3436
年,卷(期):2024.42(6)