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辐射制冷降温针织面料的制备及性能研究

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具有日间被动辐射冷却的纺织品可以减轻高温天气对人体的伤害。文章以腈纶和蚕丝两种原料为基材,以聚乙烯醇(PVA)、无机纳米粒子二氧化硅(SiO2)和三氧化二铝(Al2O3)的混合分散液为整理剂对纱线进行处理,利用手摇横机制备了两种罗纹组织的针织面料,再对织物进行盐酸刻蚀造孔处理,得到了具有高效辐射制冷效果的降温针织面料。研究表明,织物表面及纤维间被填料粒子覆盖,经盐酸刻蚀后出现均匀微孔;盐酸刻蚀得到的微孔能够明显提高织物对太阳光的反射率;与原织物相比,盐酸刻蚀后的织物在大气窗口的平均红外发射率约为87。9%,太阳反射率为75。0%,在辐照强度为501 mW/cm2时,与对照织物相比可降低温度约12℃,具有较大的应用潜力。
Preparation and Performance Study of Knitted Fabrics with Radiative Cooling
Textiles designed for daytime passive radiative cooling have the potential to alleviate the adverse effects of elevated temperatures.This study presents the preparation of two types of knitted fabrics characterized by a ribbed structure,produced using a hand-cranked flatbed machine.The utilized substrates were acrylic and silk,while the finishing agent comprised a mixed dispersion of polyvinyl alcohol(PVA),along with inorganic nanoparticles of silicon dioxide(SiO2)and aluminum trioxide(Al2O3).Subsequently,the fabrics underwent hydrochloric acid etching to introduce perforations,resulting in knitted fabrics with enhanced radiative cooling efficiency.The results indicate that filler particles covered the fabric surface and within the inter-fiber spaces,leading to the formation of uniform micropores following hydrochloric acid etching.The micropores obtained by hydrochloric acid etching can obviously improve the reflectivity of sunlight;compared with the original fabric,the average infrared emissivity of the fabric after hydrochloric acid etching in the atmospheric window is about 87.9%,and the solar reflectivity is 75.0%;the temperature can be reduced by about 12℃compared with the control fabric when the irradiation intensity is 501 mW/cm2,which has a large application potential.

radiative coolingfinishing agentrib stitchporous structure

海文清、宗雨欣、玛力瓦·革命加纳、毕思伊

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东华大学纺织学院

辐射冷却 整理剂 罗纹组织 多孔结构

2025

纺织导报
中国纺织信息中心

纺织导报

影响因子:0.306
ISSN:1003-3025
年,卷(期):2025.(1)