首页|一种新型镉基三元配位聚合物作为铁离子的发光探针以及在抗菌领域的应用

一种新型镉基三元配位聚合物作为铁离子的发光探针以及在抗菌领域的应用

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在溶剂热条件下合成了一种新型三元配位聚合物(CP),[Cd2(L)2(bimb)2]n·3DMF· 2H2O(H2L=N,N-二(4-羧基苄基)苯胺,bimb=1,4-二(1-咪唑)苯)。该合成物为二维层状结构,通过单晶X射线衍射、粉末X射线衍射、红外光谱和热重分析进行了表征。该配合物对铁离子表现出优异的检测能力,猝灭常数Ksv=3。812×104。此外,该复合物对白色念珠菌也具有良好的抑菌作用,最低抑菌浓度为20 μg·mL-1。
A novel cadmium-based ternary coordination polymer as a luminescent probe for Fe3+and application in the antibacterial field
In this paper,a novel ternary coordination polymer(CP),[Cd2(L)2(bimb)2]n·3DMF·2H2O(H2L=N,N-bis(4-carboxybenzyl)aniline,bimb=1,4-bis(1-imidazolyl)benzene),was synthesised under solvothermal conditions.The compound was characterised by single crystal X-ray diffraction,powder X-ray diffraction,infrared spectroscopy,and thermogravimetric analysis.It is proved that the complex has high purity and good thermal stability.Subsequently,different metal ions were qualitatively analysed by fluorescence detection using fluorescence spectroscopy,and after comparison,it can be concluded that the complex has a bursting effect on many metal ions,and the best bursting effect is for iron ions.In this pa-per,the antibacterial properties of the complexes were tested against Candida albicans(ATCC 10231)u-sing the circle of inhibition method and growth curve method.The antimicrobial effect of the complex was qualitatively analysed based on the circle of inhibition,and it was found that the complex had a good inhib-itory effect against Candida albicans(ATCC 10231)and a clear circle of inhibition with a large diameter could be seen on the plate.After that,the growth curve of the complex was tested to determine the mini-mum inhibitory concentration.

coordination polymer(CP)Fe3+detectioncandida albican

宋冠英、赵仑、景宏伟、王紫蕴、李佳雨、郭冠麟、韩越、王哲昕

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长春师范大学化学学院,吉林长春 130000

配位聚合物 铁离子 白色念珠菌

Science and Technology Development Planning of Jilin Province

20210101129JC

2024

分子科学学报
中国化学会

分子科学学报

CSTPCD
影响因子:0.434
ISSN:1000-9035
年,卷(期):2024.40(1)
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