分子科学学报2024,Vol.40Issue(5) :396-410.DOI:10.13563/j.cnki.jmolsci.2024.05.103

作为高性能光热转换材料的两性表面活性剂-多聚杂多蓝自组装体

Amphiphilic surfactant-heteropoly blue self-assemblies as high-performance photothermal conversion materials

赵淞莹 史明新 李英奇 姚瑞琪 王永慧 谭华桥 李阳光
分子科学学报2024,Vol.40Issue(5) :396-410.DOI:10.13563/j.cnki.jmolsci.2024.05.103

作为高性能光热转换材料的两性表面活性剂-多聚杂多蓝自组装体

Amphiphilic surfactant-heteropoly blue self-assemblies as high-performance photothermal conversion materials

赵淞莹 1史明新 1李英奇 1姚瑞琪 1王永慧 1谭华桥 1李阳光1
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作者信息

  • 1. 东北师范大学化学学院多酸与网格材料化学教育部重点实验室,吉林长春 130024
  • 折叠

摘要

探索具有优异光热转换功能的新型材料用于太阳能光热蒸发水被认为是同时实现直接和充分利用广泛分布的太阳能和缓解世界淡水匮乏的理想策略.通过亲水性杂多蓝(HPB,H3PMo12O40)和疏水性表面活性剂(双十八烷基二甲基溴化铵,DODA)的自组装制备了一种两亲性光热膜.基于二维DODA-HPB自组装的柔性膜(DODA-HPB/Nylon66)得益于功能性亲水HPB层和疏水DODA层交替出现的协同效应,表现出优异的光热转换性能,在太阳能海水淡化和废水处理方面具有广阔的应用前景.

Abstract

Exploring novel materials with excellent photothermal conversion capabilities for solar photo-thermal water evaporation is considered as an ideal strategy to simultaneously realize the direct and full use of the widely distributed solar energy and alleviate the world's freshwater scarcity.Herein,an amphiphilic photothermal membrane is prepared through the self-assembly of hydrophilic heteropoly blue(HPB,H3PMo12O40)and hydrophobic surfactant(dioctadecyl dimethyl ammonium bromide,DODA).Benefiting from the synergistic effects of alternating functional hydrophilic HPB and hydrophobic DODA layers,the flexible membrane based on two-dimensional DODA-HPB self-assemblies(DODA-HPB/Nylon66)exhibits superior photothermal conversion properties,showing promising prospects in applications of solar desali-nation and wastewater treatment.

关键词

杂多蓝/表面活性剂/自组装/光热转换/两亲性

Key words

heteropoly blue/surfactant/self-assemblies/photothermal conversion/amphiphilic

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出版年

2024
分子科学学报
中国化学会

分子科学学报

CSTPCD
影响因子:0.434
ISSN:1000-9035
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