首页|NiFe-LDH@Cu2O/PAN光催化纤维的制备及性能研究

NiFe-LDH@Cu2O/PAN光催化纤维的制备及性能研究

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针对Cu2O光催化活性较低,粉末光催化剂不易回收及重复使用性差等问题,采用静电纺丝方法制备NFC/PAN光催化纤维;通过引入可在其夹层中容纳阴离子的层状双氢氧化物,用NiFe-LDH对Cu2O进行改性,并将其负载于PAN纤维,使用扫描电子显微镜、能谱仪、万能试验机、紫外可见吸收光谱等测试方法,评价不同Ni3Fe1-LDH@Cu2O添加量对光催化纤维的性能影响.指出:在可见光照射60 min后,NFC质量百分比为5%的Ni3Fe1-LDH@Cu2O/PAN对亚甲基蓝的降解效果最佳,达到91.7%,且其比表面积为76.3 cm2/g,具有一定力学稳定性,重复使用5次后其降解率依旧达85%以上;5%Ni3Fe1-LDH@Cu2O/PAN光催化效果在短时间可达到高效率,其光催化纤维降解速率常数最大,为0.022 6,拉伸断裂强力提高3.35倍.
Preparation and Properties of NiFe-LDH@Cu2O/PAN Photocatalytic Fibers
In view of the low photocatalytic activity of Cu2O,the difficulty of recycling and the poor reuse of powder photocatalyst,NFC/PAN photocatalytic fiber is prepared by electrospin-ning.By introducing a layered double hydroxide that can contain anions in its interlayer,Cu2 O is modified by NiFe-LDH and loaded on PAN fiber.The testing methods are used to evaluate the effect of different amount of Ni3Fe1-LDH@Cu2O on the properties of photocatalytic fibers,such as scanning electron microscope,energy spectrometer,universal testing machine,UV-VIS absorption spectroscopy,etc.It is pointed out that Ni3 Fe1-LDH@Cu2O/PAN with 5%NFC mass percentage has the best degradation effect on methylene blue after 60 min of visible light irradi-ation,reaching 91.7%,with a specific surface area of 76.3 cm2/g,showing certain mechanical st-ability.The degradation rate is still above 85%after repeated use for five times.Moreover,the photocatalytic effect of 5%Ni3Fe1-LDH@Cu2O/PAN can achieve high efficiency in a short time,and the degradation rate constant of the photocatalytic fiber is the highest,which is 0.022 6,and the tensile breaking strength is increased by 3.35 times.

NiFe-LDH@Cu2O/PAN photocatalytic fiberlayered double hydroxidepolyacrylo-nitrile fiberNFCmethylene bluedegradation

高云莉、王琛、党袁鹏、司佳佳

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彬州市职业教育中心,陕西彬州 713599

西安工程大学,西安 710048

陕西彬长矿业集团有限公司,陕西咸阳 712000

陕西纺织器材杂志社有限责任公司,陕西咸阳 712000

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NiFe-LDH@Cu2O/PAN光催化纤维 层状双氢氧化物 聚丙烯腈纤维 NFC 亚甲基蓝 降解

2024

纺织器材
中国纺织信息中心 中国纺织机械器材料工业协会

纺织器材

影响因子:0.212
ISSN:1001-9634
年,卷(期):2024.51(1)
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