首页|褐煤腐植酸复合菌剂对镉离子的吸附效果和机理的初步研究

褐煤腐植酸复合菌剂对镉离子的吸附效果和机理的初步研究

扫码查看
以褐煤腐植酸复合菌剂和镉离子(Cd2+)为研究对象,进行复合菌剂吸附Cd2+试验.研究了复合菌剂添加量和pH对Cd2+吸附的影响,通过对吸附Cd2+前后复合菌剂的形貌表征及吸附动力学过程分析,初步探究了复合菌剂对Cd2+的吸附机理.研究结果表明,复合菌剂可有效吸附Cd2+,菌剂添加量和pH对Cd2+吸附效果有显著影响,当复合菌剂添加量为 12 g/L、pH=5 时,对Cd2+的吸附效果最好,最大吸附容量为 3.942 mg/g,吸附率达到 94.62%.复合菌剂对Cd2+吸附动力学符合准二级动力学方程,为单分子层吸附.复合菌剂吸附Cd2+后表面层状结构消失,表面更加粗糙凹凸不平,结构发生改变,且吸附后表面Cd元素质量百分比高于褐煤,说明褐煤复合菌剂对于Cd2+的吸附能力得到了提升.
Preliminary Study on Adsorption Effect and Mechanism of Cd2+by Composite Microbial Inoculant with Lignite Humic Acids
The composite microbial inoculant with lignite humic acids and cadmium ions(Cd2+)as research objects,Cd2+adsorption was performed.The influence of the composite microbial inoculant dosage and pH level was examined.Additionally,the adsorption mechanism of the composite microbial inoculant on Cd2+was preliminarily explored through a comprehensive analysis of its morphology and adsorption kinetics before and after the adsorption process.The results indicated that the composite microbial inoculant could effectively adsorb Cd2+,The dosage and pH had significant influence on the adsorption effect of Cd2+.The optimal conditions for adsorption were found to be a composite microbial inoculant dosage of 12 g/L and a pH of 5.Under these conditions,the maximum adsorption capacity of Cd2+reached 3.942 mg/g,with an adsorption rate of 94.62%.Furthermore,the adsorption kinetics of the composite microbial inoculant followed a quasi-second-order kinetic equation,suggesting a single molecular layer adsorption mechanism.The morphological analysis revealed that the surface layer structure of the composite microbial inoculant disappeared upon adsorption,resulting in a rougher and more uneven surface.Furthermore,the components of Cd on the absorbed surface were higher than the raw lignite,which indicated the capability of Cd2+by composite microbial inoculant with lignite humic acids was improved.

lignitehumic acidcomposite microbial inoculantCd2+adsorption kinetics

裴启航、叶尔阿森·吐地拜、茅文庆、关家栋、陈林勇、周志林、何环

展开 >

中国矿业大学化工学院煤炭加工与高效洁净利用教育部重点实验室 徐州 221116

煤与煤层气国家重点实验室 晋城 048012

徐州农业科学研究院 徐州 221131

褐煤 腐植酸 复合菌剂 镉离子 吸附动力学

国家自然科学基金项目徐州市重点研发计划项目

421721872021ZDPY0210

2024

腐植酸
中国腐植酸工业协会

腐植酸

影响因子:0.217
ISSN:1671-9212
年,卷(期):2024.(4)