工程地质学报2024,Vol.32Issue(2) :492-502.DOI:10.13544/j.cnki.jeg.2021-0825

层状灰岩酸蚀化学-力学损伤演化机制研究

STUDY ON CHEMICAL AND MECHANICAL DAMAGE EVOLUTION MECHANISM OF BEDDED LIMESTONE IN ACID CORROSION

付丽 左双英 王露 陈世万 李豪逸
工程地质学报2024,Vol.32Issue(2) :492-502.DOI:10.13544/j.cnki.jeg.2021-0825

层状灰岩酸蚀化学-力学损伤演化机制研究

STUDY ON CHEMICAL AND MECHANICAL DAMAGE EVOLUTION MECHANISM OF BEDDED LIMESTONE IN ACID CORROSION

付丽 1左双英 2王露 1陈世万 2李豪逸3
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作者信息

  • 1. 贵州大学,资源与环境工程学院,贵阳 550025,中国
  • 2. 贵州大学,资源与环境工程学院,贵阳 550025,中国;贵州大学,喀斯特地质资源与环境教育部重点实验室,贵阳 550025,中国
  • 3. 贵州大学,喀斯特地质资源与环境教育部重点实验室,贵阳 550025,中国
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摘要

为研究酸性水对碳酸盐岩溶蚀-力学特性的影响,在固定时间、常温常压状态下,将不同倾角层理的灰岩岩样分别放在pH=3、4、5的酸液中进行固定流速溶蚀试验,并对溶蚀试验后的岩样进行单轴压缩、声发射(AE)及电镜扫描试验(SEM),获得岩样酸蚀前后质量、波速、Ca2+/Mg2+浓度、峰值强度、弹性模量、声发射振铃计数等指标的变化规律,分别采用溶蚀前后波速变化、声发射累积振铃计数表征岩样的化学溶蚀损伤和力学损伤,建立灰岩全变形过程的化学-力学损伤演化方程.试验结果表明,溶液酸性强度与岩样溶蚀率成正比,与宏观力学强度成反比,并且层理倾角对溶蚀的影响程度为90°>0°>45°.在酸性环境中,灰岩内部晶体被溶解,矿物联结减弱,从而引起宏观力学参数的改变,研究结果可以为废弃矿山岩体稳定评价提供参考.

Abstract

This paper studies the influence of acidic water on the corrosion-mechanical properties of carbonate rocks.Limestone samples with different dip angles were immersed and dissolved in acid solution at a fixed flow rate and normal temperature at pH=3,4,and 5,respectively.The dissolved samples were subjected to uniaxial com-pression,acoustic emission(AE),and scanning electron microscope(SEM)tests.The changes in indicators such as mass,wave velocity,Ca2+/Mg2+ concentration,peak strength,elastic modulus,and AE ringing counts before and after acid erosion were obtained.The chemical and mechanical damage were characterized by changes in wave ve-locity and AE cumulative ringing count,and the full deformation process and chemical-mechanical damage evolu-tion equation were established.The results show that acidity of the solution is proportional to the degree of dissolu-tion of the rock sample,inversely proportional to the macroscopic mechanical strength,and the influence of dip an-gle on dissolution is 90°>0°>45°.In the acidic environment,the internal crystals of tuffs are dissolved,the mineral connections are weakened,thus causing changes in macro-mechanical parameters.The results can provide a refer-ence for the evaluation of rock stability in abandoned mines.

关键词

层状灰岩/酸性溶蚀/化学-力学损伤/损伤演化/声发射

Key words

Bedded limestone/Acid dissolution/Chemical-mechanical damage/Damage evolution/Acoustic e-mission

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基金项目

国家自然科学基金项目(42167025)

贵州省科学技术基金重点项目([2020]1Z052)

贵州省科学技术基金([2020]1Y185)

出版年

2024
工程地质学报
中国科学院地质与地球物理研究所

工程地质学报

CSTPCDCSCD北大核心
影响因子:1.215
ISSN:1004-9665
参考文献量54
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