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软质聚氨酯泡沫燃烧特性及参数敏感性

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本研究基于火焰蔓延量热仪(FPA),在不同辐射热流及样品厚度条件下,开展软质聚氨酯泡沫(FPUF)燃烧特性实验研究.结果表明,FPUF燃烧可分为三个阶段:阶段一主要为FPUF热解与甲苯二异氰酸酯(TDI)燃烧,阶段二主要为多元醇燃烧,阶段三主要为焦炭氧化.基于Box-Behnken设计方法建立质量响应模型,方差分析结果表明,模型对单个参数敏感性为:样品底面温度>辐射热流>样品厚度;多个参数敏感性为:样品底面温度×样品厚度>样品底面温度的平方>样品厚度的平方.
Combustion Characteristics and Parameter Sensitivity of Flexible Polyurethane Foam
The flexible polyurethane foam(FPUF)combustion is studied by fire propagation ap-paratus(FPA)with different radiant heat fluxes and sample thicknesses.The results show that FPUF combustion can be divided into three stages:the first stage is mainly FPUF pyrolysis and toluene diisocyanate(TDI)combustion,the second stage mainly polyol combustion,and the third stage mainly char oxidation.A mass response model is established by the Box-Behnken design method.The results of variance analysis show that the sensitivity of the mass model to the single parameter is:sample bottom temperature>radiant heat flux>sample thickness;and the sensitivity of the mass model to the combined effects of multiple parameters is:sample bot-tom temperature x sample thickness>sample bottom temperature squared>sample thickness squared.

flexible polyurethane foampyrolysiscombustionsensitivity analysisfire propagation apparatus

黄梦真、朱虹、刘乃安、谢小冬、马超、张首蕤

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中国科学技术大学火灾科学国家重点实验室,合肥 230026

软质聚氨酯泡沫 热解 燃烧 敏感性分析 火焰蔓延量热仪

国家自然科学基金国家自然科学基金中国博士后科学基金国家重点研发计划

51936011419611440122021M7030832022YEC3003000

2024

工程热物理学报
中国工程热物理学会 中国科学院工程热物理研究所

工程热物理学报

CSTPCD北大核心
影响因子:0.4
ISSN:0253-231X
年,卷(期):2024.45(2)
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