首页|利用量子对应态原理预测正仲氢输运性质

利用量子对应态原理预测正仲氢输运性质

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基于量子对应态原理并考虑氢同分异构体之间的结构差异,建立了适用于预测低温正氢与仲氢输运参数的数学模型,明确了对比黏度和对比导热系数与对比德布罗意波长之间的线性关系,并使用所建立数学模型预测了正氢与仲氢的黏度与导热系数。通过对计算结果的检验分析,发现量子对应态原理方法可以较准确地预测温度20~100K及压力0。01~10 MPa范围内正氢、仲氢的黏度及导热系数。压力对模型的预测精度影响显著,当环境压力小于1 MPa时,对应态原理预测误差基本控制在6%以内。进一步修正模型中的物性常数修正有望提高对应态原理预测精度。
Prediction of the Conductivity of O-H2 and P-H2 Based on the Quantum Law of Corresponding States
Based on the quantum law of corresponding states and considering the structural differ-ences between hydrogen isomers,a mathematical model was developed for predicting the transport parameters of low-temperature orthohydrogen and parahydrogen.The results were examined and analyzed,and it was found that the quantum correspondence state principle method could predict the viscosity and thermal conductivity of orthohydrogen and parahydrogen in the temperature range of 20~100 K and pressure range of 0.01~10 MPa with good accuracy.The pressure has a significant impact on the prediction accuracy of the model,and the prediction error of the correspondence state principle is basically controlled within 6%when the ambient pressure is less than 1 MPa.Further correction of the physical constants in the model is expected to improve the prediction accuracy of the correspondence state principle.

orthohydrogenparahydrogenviscositythermal conductivity quantum law of corre-sponding states

孟垂举、秦旭进、黄永华

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上海交通大学制冷与低温工程研究所,上海市 200240

正氢 仲氢 黏度 导热系数 量子对应态原理

国家重点研发计划国家自然科学基金

SQ2022YFE02084451936006

2024

工程热物理学报
中国工程热物理学会 中国科学院工程热物理研究所

工程热物理学报

CSTPCD北大核心
影响因子:0.4
ISSN:0253-231X
年,卷(期):2024.45(3)
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