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湍流旋流氨气-甲烷预混火焰燃烧特性研究

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为了研究NH3-CH4掺混燃气的燃烧特性,设计了一个可视化的旋流湍流燃烧装置,通过实验对当量比(φ)、氨气掺混比(XNH3)和入口空气流量对燃烧特性的影响进行分析。结果表明:随着当量比增加,燃烧室出口 NO排放先增加后减小,在φ=0。9时达到峰值,对其反应速率和燃烧光谱进行分析,发现NO2和HNO浓度协同影响了 NO的反应速率,NO排放和OH基强度呈正相关,NH2α基和H2O蒸气产生的链式反应促进了 NO的还原。随着XNH3升高,火焰由蓝色逐渐转变为橙黄色,NO排放先增加后减少,在XNH3=0。4附近出现峰值。另外,随着入口空气流量的增加,气流速度增大导致湍流强度增大,贫燃状态下NO排放增加,而在富燃状态下排放减少,文中对其中机理进行了分析。
Study on Combustion Characteristics of Turbulent Rotating Ammonia-Methane Premixed Flame
A visualized turbulent swirling combustion device was designed to investigate the com-bustion characteristics of NH3-CH4 mixture.The experiments focused on analyzing the impact of equivalence ratio,ammonia mixing ratio(XNH3),and inlet air flow rate on the combustion pro-cess.The results indicated that as the equivalence ratio increased,nitrogen oxide(NO)emissions at the combustion chamber outlet first increased and then decreased,reaching a peak at φ=0.9.Analysis of the combustion spectrum revealed that a positive correlation between NO emissions and OH radical intensity.Chain reactions generated by NH2α radicals and water vapor promote the reduction of NO.Moreover,as XNH3 increased,the flame transitioned from blue to orange-yellow,with NO emissions showing a similar trend of first increasing and then decreasing,peaking around XNH3=0.4.Furthermore,NO emission was found to increase with inlet air flow rate during lean com-bustion but decrease it during rich combustion.The underlying mechanism for this phenomenon is analyzed.

ammonia combustionturbulent swirling flamenitric oxide emissionexperimental measurementcombustion characteristics

刘文锋、帅瑞洋、王平、钱伟佳、王永倩、杨证淳、张泽雨、Antonio Ferrante

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江苏大学能源研究院,镇江 212013

浙江大学能源清洁利用国家重点实验室,杭州 310027

能源与环境中心,Gioia del Colle(BA),意大利米兰70023

氨气燃烧 旋流湍流火焰 一氧化氮排放 实验测量 燃烧特性

国家自然科学基金浙江大学能源清洁利用国家重点实验室开放基金

91741117ZJUCEU2022020

2024

工程热物理学报
中国工程热物理学会 中国科学院工程热物理研究所

工程热物理学报

CSTPCD北大核心
影响因子:0.4
ISSN:0253-231X
年,卷(期):2024.45(6)
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