首页|材料VOC/SVOC散发解析模型及参数测定方法研究

材料VOC/SVOC散发解析模型及参数测定方法研究

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室内建材和家具散发的挥发性有机物(VOC)及半挥发性有机物(SVOC)对人类健康的影响不容忽视。本文首先建立了材料中VOC及SVOC散发过程的统一解析模型,其有助于实现源/汇特性的统一表征及对污染物的综合控制。并利用混合优化方法来获得模型中的散发关键参数,包括初始可散发浓度C0、扩散系数Dm、材料/空气分配系数Km及环境舱表面/空气分配系数Ks。基于实木家具中VOC散发的实验数据,以及文献中一种阻燃剂SVOC散发的数据,验证了模型及方法的有效性。此外,还分析了不同温度下SVOC长期散发对材料表面气相浓度(Y0)的影响规律。结果表明,温度较高或散发时间较长时,用C0代替传统研究中的y0作为散发关键参数更为合适。
Research on the VOC/SVOC Emission Analytical Model and Parameter Measurement Method
The impact of emitted volatile organic compounds(VOC)and semi-volatile organic compounds(SVOC)from indoor building materials and furniture cannot be ignored.This study firstly establishes a unified analytical model to describe the emissions of VOC/SVOC from materials,which is helpful for the achievement of general characterization of source/sink behaviors and the integrated control of pollutants.A hybrid optimization method is used to measure the three key parameters in the model,including the initial emittable concentration(C0),diffusion coefficient(Dm),material/air partition coefficient(Km),and surface/air partition coefficient(Ks).Data of VOC emissions from a solid wood furniture and SVOC emissions a flame retardant in literature are used to verify the validity of the model and method.Moreover,the impact of long-term SVOC emission on the gas-phase concentration along the material surface(y0)at different temperatures is analyzed.Results indicate that,with the increase of temperature or emission time,it is more appropriate to use C0 as a key emission parameter,rather than the widely used y0 in prior studies.

volatile organic compounds(VOC)semi-volatile organic compounds(SVOC)key emission parametersmass transferindoor environment

张宣凯、熊建银

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北京理工大学机械与车辆学院,北京 100081

挥发性有机物(VOC) 半挥发性有机物(SVOC) 散发关键参数 传质 室内环境

国家自然科学基金

52178062

2024

工程热物理学报
中国工程热物理学会 中国科学院工程热物理研究所

工程热物理学报

CSTPCD北大核心
影响因子:0.4
ISSN:0253-231X
年,卷(期):2024.45(6)