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反应热历程对微波辅助生物质热解产物的影响机制

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微波辅助生物质热解中复杂的能-热转化过程对产品性质具有重要影响.本研究考察了不同工况下微波辅助生物质热解热历程和产物分布特性,建立了微波辅助生物质热解过程中电磁波-热量传递方程与热解反应动力学相互耦合数值模型.结果表明,与常规热解相比微波辅助热解独特的热历程导致热解气中合成气(CO+H2)的产率提升(0.71~7.43倍);对生物油中芳烃组分的选择性增加(4.87%~18.8%).通过改变微波吸收剂介电性能、添加比例和微波功率调变反应热历程,一定程度上实现了对产物组成的定向调控.
The Influences of Thermal History on Product Characteristics During Microwave-assistant Pyrolysis of Biomass
The complex energy and heat conversion processes in microwave-assisted biomass pyrol-ysis have important effects on product properties.In this study,the thermal history and product distribution characteristics of microwave-assisted biomass pyrolysis under different operating con-ditions were investigated.To detect the mechanism,a numerical model coupled pyrolysis reaction kinetics and the equations of electromagnetic wave and heat transfer for the microwave-assisted biomass pyrolysis was established.The results indicate that,in comparison to conventional pyrol-ysis,the distinctive thermal profile of microwave-assisted pyrolysis results in a 0.71 to 7.43 times increase in the synthesis gas yield(CO+H2)in the pyrolysis gas,along with a 4.87%to 18.8%rise in the selectivity of aromatic hydrocarbon components in bio-oil.By altering the dielectric properties and addition ratio of the microwave absorber,as well as the microwave power,we achieve a certain degree of directional control over the product composition by regulating the heat history during microwave-assistant pyrolysis of biomass.

biomassmicrowave-assisted pyrolysisproduct characterizationnumerical simulationthermal history

孙道广、李方舟、仰科、张会岩

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东南大学能源热转换及其过程测控教育部重点实验室,南京 210096

生物质 微波辅助热解 产物特征 数值模拟 热历程

国家自然科学基金青年科学基金项目国家自然科学区域创新与发展联合基金重点项目

52206238U23A20641

2024

工程热物理学报
中国工程热物理学会 中国科学院工程热物理研究所

工程热物理学报

CSTPCD北大核心
影响因子:0.4
ISSN:0253-231X
年,卷(期):2024.45(9)