首页|PC/铜负载氧化石墨烯复合材料的抗菌性能

PC/铜负载氧化石墨烯复合材料的抗菌性能

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聚碳酸酯(PC)是一种具有优异综合性能的工程塑料,在抗菌产品的应用中,改进PC材料的短效抗菌性能和耐洗刷性能,可提高其抗菌效率和使用寿命.通过液相混合和喷雾干燥工艺,在不同氧化石墨烯(GO)和硫酸铜添加比例条件下,合成了三种铜负载氧化石墨烯抗菌剂(Cu@GO).随后,将抗菌剂与PC进行混合和注塑,制备了一系列PC/铜负载氧化石墨烯复合材料(PC/Cu@GO).测试了三种PC/Cu@GO复合材料的常规抗菌性能、高效抗菌性能和耐洗刷性能.结果表明,Cu@GO抗菌剂能够显著提升PC的抗菌性能,当GO与硫酸铜添加比为1∶9时,对应PC的短时间抗菌性能优异,接种6 h,其对大肠杆菌和金黄葡萄球菌的抗菌率为96.8%和70.0%.当GO与硫酸铜质量比为1∶3时,经洗刷后PC的抗菌耐久性较好,经过4次洗刷和浸泡处理后,其对大肠杆菌和金黄葡萄球菌的抗菌率仍保持在68.2%和61.7%.
Antibacterial properties of PC/copper-loaded graphene oxide composites
Polycarbonate(PC)is an engineering plastic with excellent combination properties.In the application of antibacteri-al products,the antibacterial efficiency and service life of PC could be improved by improving its short-trem antibacterial property and scrub resistance.The Cu@graphene oxide(GO)antibacterial agents were synthesized through liquid phase mixing and spray drying under varying ratios of GO and copper sulfate,resulting in three distinct types.Subsequently,a series of PC/Cu@GO composites were prepared by blending and injection molding the antibacterial agents with PC.The conventional antibacterial perfor-mance,the short-term antibacterial property,and the scrub resistance of three PC/Cu@GO materials were evaluated.The results demonstrate that the Cu@GO antibacterial agent significantly enhances the antibacterial performance of PC.Specifically,when the addition ratio of GO to copper sulfate is 1∶9,the corresponding PC exhibites favorable short-trem antibacterial property with the antimicrobial rates of 96.8%and 70.0%,after 6 hours of Escherichia coli and Staphylococcus aureus inoculation.When the addition ratio of GO to copper sulfate is 1∶3,the corresponding PC displayed excellent long-lasting bactericidal efficacy as evidenced by sustained antimicrobial rates of 68.2%for Escherichia coli and 61.7%for Staphylococcus aureus after four cycles of washing and soaking treatment.

copper-loaded graphene oxidepolycarbonateantibacterial propertyshort-term antibacterial propertyscrub resistance

梁佳丰、李岳

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中国航发北京航空材料研究院,北京 100095

铜负载氧化石墨烯 聚碳酸酯 抗菌性能 短时间抗菌性能 耐洗刷性能

国家自然科学基金北京市科技新星计划

51802296Z191100001119102

2024

工程塑料应用
中国兵器工业集团第五三研究所 中国兵工学会非金属专业委员会 兵器工业非金属材料专业情报网

工程塑料应用

CSTPCD北大核心
影响因子:0.371
ISSN:1001-3539
年,卷(期):2024.52(3)
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