首页|环境吸湿对玻璃纤维增强尼龙66材料性能的影响

环境吸湿对玻璃纤维增强尼龙66材料性能的影响

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通过研究两种玻璃纤维(GF)增强尼龙(PA)[GF增强PA66(A3WG6,巴斯夫),简称复合材料A;自制PA66+30%GF,简称复合材料B]在环境温湿度条件下调节不同时间后的吸湿状态,探讨了不同时间调节后PA复合材料的拉伸强度、拉伸弹性模量、拉伸应变、冲击强度及收缩率与调节时间的关系,考察了材料在常温环境下调节时间与材料含水率的关系,同时分析了水分对PA复合材料性能影响的机理.结果表明,在试验范围内,PA复合材料在常温环境中的吸湿率随着调节时间的延长而增加,环境吸湿速率在16 h达到最高,在168 h后趋于平稳.吸湿后的PA复合材料拉伸强度随着调节时间的延长逐渐下降,拉伸应变和拉伸弹性模量变化相对较小,冲击强度则随着调节时间的延长逐渐增大.当PA66复合材料A、B在环境温湿度条件下调节168 h后,材料的含水率分别为0.207%和0.145%,材料的拉伸强度分别下降了14 MPa和15.3 MPa,损失率达到6.9%和7.8%.当PA66复合材料A、B在环境温湿度条件下调节960 h后,材料的含水率分别为0.578%和0.439%,材料的拉伸强度分别下降了38 MPa和35 MPa,损失率分别达到18.6%和18.2%,材料的冲击强度则提高了12.3%和45.7%.PA66复合材料A、B在相同环境温湿度条件下调节不同时间后的物理力学性能、吸湿状态呈相同趋势.
Effect of environmental hygroscopicity on properties of GF reinforced nylon 66 materials
By studying the hygroscopic states of two kinds of glass fiber(GF)reinforced nylon(PA)[GF reinforced PA66(A3WG6,BASF),referred to as composite A,self-made PA66+30%GF,referred to as composite B]after adjustment of different time under ambient temperature and humidity conditions,the relationship between the tensile strength,tensile modulus,tensile strain,impact strength and shrinkage rate of PA composites after adjustment of different time and adjustment time was discussed.The relationship between the adjusting time and the moisture content of the material at room temperature was investigated,and the mechanism of the influence of moisture on the properties of the PA composites was analyzed.The results show that in the experimen-tal range,the moisture absorption rate of PA composites in normal temperature environment increases with the extension of regula-tion time.The environmental moisture absorption rate reaches the highest at 16 h,and tends to be stable after 168 h.The tensile strength of PA composites decrease gradually with the extension of adjusting time,the tensile strain and tensile modulus change rela-tively little,and the impact strength increase gradually with the extension of adjusting time.When PA 66 composites A and B are adjusted under ambient temperature and humidity conditions for 168 h,the water content of the composites is 0.207%and 0.145%respectively.The tensile strength of PA composites decrease by 14 MPa and 15.3 MPa respectively,and the loss rate reach 6.9%and 7.8%.When PA composites A and B are adjusted for 960 h under ambient temperature and humidity conditions,the water content of the composites is 0.578%and 0.439%,respectively.The tensile strength of the composites decrease by 38 MPa and 35 MPa,the loss rate reach 18.6%and 18.2%,respectively,and the impact strength of the composites increase by 12.3%and 45.7%.The physical and mechanical properties,hygroscopic state of PA 66 composite A and B show the same trend after adjusting for different time under the same ambient temperature and humidity conditions.

glass fiber reinforced nylon compositehygroscopicmoisture contentperformanceadjust time

龚梦晴、武金龙

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安徽中翰高分子科技有限公司,安徽宣城 242300

北方民族大学材料科学与工程学院,银川 750021

玻璃纤维增强尼龙复合材料 吸湿 含水率 性能 调节时间

2024

工程塑料应用
中国兵器工业集团第五三研究所 中国兵工学会非金属专业委员会 兵器工业非金属材料专业情报网

工程塑料应用

CSTPCD北大核心
影响因子:0.371
ISSN:1001-3539
年,卷(期):2024.52(5)
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