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回收碳纤维/剑麻增强聚丙烯复合材料的力学性能

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为提高回收碳纤维(RCF)的高值化应用,采用湿法非织造成型工艺制备了碳纤维(CF)复合材料预成型体(CFP).同时为避免复合成型过程中,湿法预成型体中黏合剂在加热过程中对复合成型产生影响,采用剑麻纤维(SF)与RCF混杂成型,利用SF间氢键作用提高CFP的可成型性,从而获得了CF/SFP预成型体.另外,还制备了SF预成型体(SFP).以聚丙烯(PP)为基体,湿法非织造织物为预成型体,采用模压成型方式制备了3种PP基复合材料(CFPC,SFPC,CF/SFPC),并对以不同纤维组分形成的预成型体结构性能及PP基复合材料的力学性能进行测试,分析SF与CF混杂对湿法预成型体结构性能及PP基复合材料力学性能的影响.结果表明,在无黏合剂的条件下,RCF可通过与SF混杂,形成具有稳定结构和力学性能的CF/SFP,且混杂工艺可改善预成型体的结构均匀性及湿法成型过程中CF的质量损失率;当以SF与RCF混杂质量比3∶1制备CF/SFP时,较制备CFP时的纤维损失率下降了33.63%,厚度不匀率下降了35.03%.以湿法非织造织物形式存在的CFPC具有较好的力学性能,特别是在改善韧性方面.CFPC的拉伸应变可达到7%左右,弯曲强度达到60.01 MPa,冲击强度可达到10.12 kJ/m2.采用RCF与SF混杂制备的CF/SFPC的力学性能较SFPC的力学性能有较大改善,在增强纤维含量相同的情况下,CF/SFPC较SFPC弯曲强度和冲击强度分别提高了13.09%和18.42%.
Mechanical properties of recycled carbon fiber/sisal reinforced polypropylene composites
To improve the high-value application of recycled carbon fiber(RCF),carbon fiber(CF)preform(CFP)was prepared by wet nonwoven forming process.In order to avoid the influence of the binder in the wet preform on the composite forming during the heating process in the composite forming process,sisal fiber(SF)and RCF were mixed to improve the formabili-ty of CFP by hydrogen bonding between SF,then CF/SFP preforms were obtained.In addition,SF preforms(SFP)were prepared.Three kinds of PP-based composites(CFPC,SFPC,CF/SFPC)were prepared by compression molding with polypropylene(PP)as matrix and wet nonwoven fabric as preform.The structural properties of preforms formed by different fiber components and the mechanical properties of the polypropylene composites were tested.The effects of SF hybrid on the structural properties of wet preform and the mechanical properties of polypropylene composites were analyzed.The results show that the RCF can be mixed with SF to form a nonwoven preform with stable structure and mechanical properties under the condition of no binder.The hybrid process can improve the structural uniformity of the preform and the loss rate of CF in the wet forming process.When the SF with a mass ratio of 3∶1 is mixed with the RCF to prepare the wet preform,the fiber loss rate can be reduced by 33.63%,and the thickness unevenness is reduced by 35.03%.CFPC in the form of wet-laid nonwoven fabrics have good mechanical properties,especially in terms of toughness improvement.The tensile strain of CFPC can reach about 7%,the bending strength can reach 60.01 MPa,and the impact strength can reach 10.12 kJ/m2.The mechanical properties of CFPC can be effectively improved by mixing RCF with SF.The mechanical properties of CF/SFP prepared by mixing RCF and SF are much better than those of SFPC.Compared with SFPC,the flexural strength and impact strength of CF/SFPC increased by 13.09% and 18.42%,respectively.

recycled carbon fiberwet nonwovenhybridcompositemechanical property

胡黄飞、王凯、江舒、胡侨乐、徐珍珍、杨莉

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安徽工程大学纺织服装学院,安徽芜湖 241000

回收碳纤维 湿法非织造 混杂 复合材料 力学性能

安徽省教育厅项目2023芜湖市科技项目

2022AH0509912023yf072

2024

工程塑料应用
中国兵器工业集团第五三研究所 中国兵工学会非金属专业委员会 兵器工业非金属材料专业情报网

工程塑料应用

CSTPCD北大核心
影响因子:0.371
ISSN:1001-3539
年,卷(期):2024.52(7)
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