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黑色PA6材料的激光标记性能

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为研究黑色尼龙6(PA6)材料的激光标记性能,以PA6为基体树脂,炭黑为着色剂和激光吸收助剂,通过双螺杆挤出机熔融共混制备黑色PA6材料.使用光纤激光打标机对黑色PA6材料进行激光标记,通过分光光度仪测试未标记与已标记区域色差△L值和肉眼观察评价黑色PA6材料的标记效果.研究了不同炭黑添加量和炭黑粒径对PA6材料黑度和激光标记效果的影响,同时研究激光标记工艺对黑色PA6材料激光标记效果的影响.结果显示:随炭黑含量的增加,PA6材料黑度L值先越来越小后趋于平衡,而激光标记效果先逐渐变好,再慢慢变差,炭黑的最优添加量在0.1%~0.2%;随炭黑粒径的增加,黑色PA6材料的黑度L值先变小后变大,激光标记效果△L值先变好后变差,炭黑添加量越多,粒径的影响就越小;激光标记仪的工艺参数(速度、功率、频率)影响黑色PA6材料的激光标记效果,其中速度和功率的影响最大;炭黑添加质量分数为0.1%时,速度、功率对激光标记效果的影响最敏感,工艺调整空间大,而炭黑的添加量多时,工艺对黑色PA6材料的激光标记敏感度降低.
Laser engraving performance of black PA6 material
In order to study the laser marking performance of black nylon6(PA6)material,PA6 was used as the matrix resin,carbon black as the colorant and laser absorption additive,and black PA6 material was prepared by melt blending by using a twin-screw extruder.A fiber laser marking machine was used to laser mtark black PA6 material,and evaluate the marking effect of black PA6 material by measuring the color difference △L value between unmarked and marked areas using a spectrophotometer and observing it with the naked eye.The effects of different amounts and particle sizes of carbon black on the blackness and laser marking effect of PA6 materials were studied,and the influence of laser marking technology on the laser marking effect of black PA6 materials was also investigated.The results show that with the increase of carbon black content,the blackness L value of PA6 material first decreases and then tends to balance,while the laser marking effect gradually improves and then gradually deteriorates.The optimal amount of carbon black added is between 0.1%-0.2%.As the particle size of carbon black increases,the blackness L value of black PA6 material first decreases and then increases,and the laser marking effect △L value first improves and then deterio-rates.The more carbon black is added,the smaller the impact of particle size.The process parameters(speed,power,frequency)of the laser marking instrument affect the laser marking effect of black PA6 material,with speed and power having the greatest impact.When the amount of carbon black added is 0.1%,the effect of speed and power on laser marking is most sensitive,and there is a large space for process adjustment.However,when the amount of carbon black added is high,the sensitivity of the process to laser marking of black PA6 material decreases.

laser engravinglaser carving processnylon6carbon blackcarbon black particle size

周雷

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重庆科聚孚新材料有限责任公司,重庆 401332

中煤科工集团重庆研究院有限公司,重庆 400039

激光标记 激光标记工艺 尼龙6 炭黑 炭黑粒径

天地科技股份有限公司科技创新创业资金专项项目

2024-TD-ZD021-02

2024

工程塑料应用
中国兵器工业集团第五三研究所 中国兵工学会非金属专业委员会 兵器工业非金属材料专业情报网

工程塑料应用

CSTPCD北大核心
影响因子:0.371
ISSN:1001-3539
年,卷(期):2024.52(8)