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O2/CO2气氛下煤粉燃烧SO2排放特性

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为研究O2/CO2气氛下煤粉燃烧SO2排放特性,在沉降炉上通过模拟电厂混煤掺烧的实际工况,分析了过量空气系数α、CO2体积分数、炉膛温度以及燃料比对单煤及混煤燃烧时SO2排放特性的影响.结果显示:①α由0.8增至1.4,所选煤种SO2的排放质量浓度(以下简称"排放浓度")越大,CO的排放浓度越小;②O2/CO2气氛下SO2排放浓度低于O2/N2气氛下SO2排放浓度,降低量约为10%;③随着反应气氛里CO2体积分数由20%增加至50%,所选煤种SO2排放浓度均逐渐降低,CO的排放浓度均逐渐升高;④随着炉膛温度的升高,O2/CO2、O2/N2气氛下SO2排放浓度均增大,不同气氛、不同升温段时SO2排放浓度曲线斜率变化不同;⑤燃料比越小,煤粉燃烧越好,燃料中S向SO2的转化率越高,而高温富氧下,燃料含S量越高,SO2排放量也越高,但S向SO2的转化率下降.
SO2 Emission Characteristic of Pulverized Coal Combustion in O2/CO2 Atmosphere
In order to study SO2 emission characteristic of pulverized coal combustion in O2/CO2 atmosphere, this paper analyzes influence of excess air coefficient, CO2 volume fraction, furnace temperature and fuel ratio on SO2 emission characteristic at the time of single coal combustion and mixed coal combustion by simulating actual condition of mixed coal combustion in the power plant. Results show that excess air coefficient increases from 0.8 to 1.4 and the higher SO2 emission mass concentration (thereafter as emission concentration) is, the lower CO emission concentration is. SO2 emission concentration in O2/CO2 atmosphere which has decreased 10% is less than that in O2/N2 atmosphere. As CO2 volume fraction in reaction atmosphere increases from 20% to 50%, SO2 emission concentration gradually reduces while CO emission concentration gradually increases. With rise of furnace temperature, SO2 emission concentration in O2/CO2 and O2/N2 atmosphere both increases while changes of SO2 emission concentration curve slopes in different atmosphere and temperature rise time periods are different. In addition, the less fuel ratio is, the better combustion of pulverized coal is and the higher conversion percentage of S to SO2 in fuel is. In high temperature and enriched oxygen atmosphere, the higher S content in fuel is, the higher SO2 emission is , but conversion percentage of S to SO2decreases.

O2/CO2 atmospherepulverized coal combustionmixed combustionfuel ratioemission concentrationoxygen-enriched combustionexcess air coefficient

刘雄伟、马文静、原辉、陈启召、刘彦丰

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华北电力大学 能源动力与机械工程学院,河北 保定 071003

O2/CO2气氛 煤粉燃烧 混燃 燃料比 排放浓度 富氧燃烧 过量空气系数

2017

广东电力
广东电网公司电力科学研究院,广东省电机工程学会

广东电力

CSTPCD
影响因子:0.527
ISSN:1007-290X
年,卷(期):2017.30(5)
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