首页|新型SF6环保替代绝缘介质CF3SCF3热动与输运特性

新型SF6环保替代绝缘介质CF3SCF3热动与输运特性

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电力绝缘设备中广泛应用的SF6气体因其极强的温室效应持续危害气候安全,新型环保气体CF3SCF3有望成为替代SF6的绝缘气体.针对这一前景,对比评估CF3SCF3的基础物理特征参数,并基于吉布斯自由能最小化原理以及Chapman-Enskog理论,研究其作为电力开关设备中灭弧介质的热动与输运性质.结果表明:与大多数环保气体相比,CF3SCF3表现出较好的能量耗散能力与灭弧特性,具备开关装备应用潜力;气压的变化会影响CF3SCF3等离子体中的化学反应进程以及粒子间的相互作用强度,同时改变系统中各类粒子数密度,进而影响其热物理性质;向N2气体中添加摩尔比25%的CF3SCF3可以将纯N2在5 000 K以下的热耗散参数(质量密度与比热容的乘积)提升约2.5倍以上,且CF3SCF3-N2混合物的物理特征与CF3SCF3相似,具备作为高气压下灭弧介质的可能.研究结果为开断过程中CF3SCF3环保气体的电弧建模仿真提供了必要基础数据,有助于进一步研究其灭弧特性.
Thermodynamic and Transport Properties of CF3SCF3 as Environmentally Friendly Alternative Insulation Medium for SF6
SF6 gas,widely used in electrical insulation equipment,poses a significant threat to climate safety due to its potent greenhouse effect.The novel eco-friendly gas CF3SCF3 has emerged as a promising alternative insulating gas to replace SF6.In view of this,this study comparatively evaluates the fundamental physical properties of CF3 SCF3,and based on the principles of Gibbs free energy minimization and Chapman-Enskog theory,investigates its thermodynamic and transport properties as an arc-extinguishing medium in electrical switchgear.The results indicate that CF3SCF3 exhibits superior energy dissipation capability and arc extinguishing characteristics compared to most eco-friendly gases,making it a promising candidate for switchgear applications.Changes in pressure affect the chemical reaction processes and inter-particle interaction strengths in CF3SCF3 plasma,thereby altering the densities of various particles in the system and impacting its thermophysical properties.Adding 25%CF3SCF3 to N2 gas can enhance its thermal dissipation parameter(product of mass density and specific heat capacity)by more than 2.5 times below 5 000 K.The physical characteristics of CF3SCF3-N2 mixtures are similar to those of CF3 SCF3,suggesting their potential as arc extinguishing media under high-pressure conditions.This study provides essential data for modeling and simulating the arc interruption process of CF3SCF3 eco-friendly gas,contributing significantly to further research on its arc extinguishing properties.

CF3SCF3SF6 alternative gasparticle compositionthermodynamic propertytransport coefficientarc plasma

李兴文、汪冠宇、唐念、孙东伟、郑晓光、张博雅

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电工材料电气绝缘全国重点实验室(西安交通大学),陕西西安 710049

广东电网有限责任公司电力科学研究院,广东广州 510080

CF3SCF3 SF6替代气体 粒子组分 热动属性 输运系数 电弧等离子体

国家重点研发计划项目中国南方电网有限责任公司科技项目

2022YFE0129500GDKJXM20220361

2024

广东电力
广东电网公司电力科学研究院,广东省电机工程学会

广东电力

CSTPCD北大核心
影响因子:0.527
ISSN:1007-290X
年,卷(期):2024.37(9)
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