首页|O2对三元混合气体C4F7N/CO2/O2中界面闪络及固体析出特性的影响研究

O2对三元混合气体C4F7N/CO2/O2中界面闪络及固体析出特性的影响研究

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在环保气体C4F7N/CO2中加入一定量O2组成三元混合气体后,可以限制C4F7N深度分解形成固体产物,因此在部分环保替代方案中得到应用;然而,O2的引入对气固界面放电特性以及固体产物形成特性的影响尚未得到深入研究,当前多数三元混合气体方案中O2含量缺乏依据.为探究合适的O2混合比例,研究C4F7N/CO2/O2三元混合气体下的气固界面闪络特性,获得O2含量、C4F7N含量等对闪络电压的影响;分析三元混合气体下气固界面闪络放电电流以及放电后的界面宏观、微观图像.结果表明:O2含量对闪络放电电压、放电电流幅值总体影响不大,制订混合方案时可主要考虑其对分解特性的影响;o2含量过高时会促进气体-电极-绝缘材料三结合点附近区域的烧蚀现象,增强放电通道中的气体热解过程,从而形成烧蚀坑或黑色固体产物堆积,影响系统的绝缘水平;实际应用中O2含量不宜超过6%.
Study on Influence of O2 on Interface Flashover and Solid Precipitation Characteristics in Ternary Gas Mixture C4F7N/CO2/O2
By adding a certain amount of O2 to the eco-friendly gas mixture C4F7N/CO2 to form a ternary gas mixture,the deep decomposition of C4F7N and the formation of solid by-products can be restricted.This approach has thus found application in some eco-friendly substitution solutions.However,the specific effects of O2 introduction on gas-solid interface discharge characteristics and solid by-product formation have not been thoroughly investigated.Currently,the O2 content in most ternary gas mixture schemes lacks a solid basis.To explore the appropriate oxygen mixing ratio,this paper investigates the gas-solid interface flashover characteristics of the C4F7N/CO2/O2 ternary gas mixture.The study examines the effects of O2 content and C4F7N content on flashover voltage.Additionally,it analyzes the flashover discharge current at the gas-solid interface and the macroscopic/microscopic images of the interface after discharge under the ternary gas mixture.The results indicate that the O2 content has minimal overall impact on flashover discharge voltage and discharge current amplitude.Therefore,when formulating the mixture scheme,the primary consideration should be its effect on decomposition characteristics.However,a high O2 content can exacerbate erosion near the triple junction of gas,electrode,and insulation material,enhancing the gas pyrolysis process within the discharge channel,leading to the formation of erosion pits or accumulation of black solid by-products,which negatively impact the system's insulation level.In practical applications,the O2 content should not exceed 6%.

C4F7Neco-friendly gasflashover characteristicgas-solid interfacesolid product

孙东伟、伍洁、唐念、唐文强、刘祖龙、钟理鹏、李良忠、刘国特

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广东电网有限责任公司电力科学研究院,广东广州 510080

湖南大学,湖南长沙 410000

中国科学院广州能源研究所,广东 广州 510630

佛山大学 机电工程与自动化学院,广东佛山 528225

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C4F7N 环保气体 闪络特性 气固界面 固体产物

国家自然科学基金项目中国南方电网有限责任公司科技项目

52107147GDKJXM20198165

2024

广东电力
广东电网公司电力科学研究院,广东省电机工程学会

广东电力

CSTPCD北大核心
影响因子:0.527
ISSN:1007-290X
年,卷(期):2024.37(9)
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