广东电力2024,Vol.37Issue(9) :72-79.DOI:10.3969/j.issn.1007-290X.2024.09.009

基于亚胺键的环保型环氧树脂的制备与再生

Preparation and Regeneration of Environmentally Friendly Epoxy Based on Imine Bond

韦雅荣 饶夏锦 张磊 张炜 黎大健 陈梁远 赵丰 彭博雅
广东电力2024,Vol.37Issue(9) :72-79.DOI:10.3969/j.issn.1007-290X.2024.09.009

基于亚胺键的环保型环氧树脂的制备与再生

Preparation and Regeneration of Environmentally Friendly Epoxy Based on Imine Bond

韦雅荣 1饶夏锦 2张磊 1张炜 1黎大健 1陈梁远 1赵丰 3彭博雅1
扫码查看

作者信息

  • 1. 广西电网有限责任公司电力科学研究院,广西南宁 530000
  • 2. 广西电网有限责任公司电力科学研究院,广西南宁 530000;广西电力装备智能控制与运维重点实验室,广西南宁 530000;广西电网设备监测及诊断工程技术研究中心,广西 南宁 530000
  • 3. 南方电网广西来宾供电局,广西 来宾 545700
  • 折叠

摘要

为改善环氧树脂电气设备粉碎、填埋等不环保的处理方式的现状,以生物基香草醛与环氧氯丙烷合成单环氧化物,并与二胺固化剂固化原位形成亚胺键结构,得到生物基环保环氧绝缘材料.该生物基环保环氧树脂在0.3 mol/50 mL盐酸混合溶剂(甲醇与水的体积比为6∶4,80 ℃)时降解速度最快,在40 min内能完全降解.由0.5 mm粉碎颗粒在140 ℃、5 Mpa压力下再生的环氧树脂玻璃化转变温度为114.86 ℃,击穿电场强度为44.08 kV/mm,性能保持率达到95%,并且可以在在弱酸环境中完全降解.退役后的环氧树脂粉碎为细小颗粒后,在高温高压的环境下能再生且性能良好.

Abstract

To improve the environmentally unfriendly disposal methods such as crushing and landfilling of epoxy resin electrical equipment,this study focuses on synthesizing monocyclic epoxy compounds from bio-based vanillin and epichlorohydrin.These compounds are then cured in situ with a diamine curing agent to form Schiff base structures,resulting in bio-based environmentally friendly epoxy insulation materials.The degradation rate of this bio-based epoxy resin is fastest in a 0.3 mol/50 mL hydrochloric acid mixed solvent(methanol/water is 6/4,v/v,80 C),with complete degradation achievable within 40 minutes.The glass transition temperature of the regenerated epoxy resin particles,crushed to 0.5 mm,is 114.86 ℃ at 140 ℃ and 5 MPa pressure,with a retention rate of 95%.The breakdown field strength is 44.08 kV/mm with a retention rate of 98%,and it can completely degrade in a weak acid environment.After the epoxy resin is ground into fine particles after retirement,it can be regenerated and performs well under high temperature and high pressure environments.

关键词

绝缘材料/环保型环氧树脂/生物基/再生

Key words

insulation material/environmentally friendly epoxy resin/bio-based/regeneration

引用本文复制引用

基金项目

广西电网有限责任公司科技项目(GXKJXM20220070)

出版年

2024
广东电力
广东电网公司电力科学研究院,广东省电机工程学会

广东电力

CSTPCD北大核心
影响因子:0.527
ISSN:1007-290X
参考文献量3
段落导航相关论文