首页|短时高热对共混聚丙烯电缆绝缘微观结构及电气性能的影响

短时高热对共混聚丙烯电缆绝缘微观结构及电气性能的影响

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在"双碳"背景的推动下,聚丙烯(polypropylene,PP)/弹性体共混物(以下简称"共混PP")被视作极具应用潜力的可回收型电缆主绝缘材料.以共混PP电缆绝缘层切片作为研究对象,模拟电缆故障时绝缘层的短时高热现象,研究短时高热对共混PP绝缘微观结构与电气性能的影响.首先,从电缆绝缘层提取试样并对其进行短时高热处理;其次,对比短时高热处理前后绝缘试样的理化性能和电气性能;最后,讨论短时高热处理过程中共混PP电缆绝缘内部微观结构变化,并分析绝缘微观结构的变化对其电气性能的影响机理.研究结果表明:电缆绝缘在经历短时高热处理后,绝缘相连续性变差,弹性体相面积减小,两相间的界面增多;试样内部分子链断裂,结晶度下降2.42%;工频下,试样介电常数上升0.04,介质损耗上升0.001 04;试样内部深陷阱数量增多,击穿电场强度下降1.4%.
Effect of Short Time and High Temperature on the Microstructure and Electrical Properties of Insulation of Blended Polypropylene Cable
Under the promotion of the"dual carbon"background,elastomer/polypropylene(PP)blends are regarded as recyclable cable main insulation materials with great application potential.In this paper,the blend polypropylene cable insulation layer slice is used as the research object to simulate the short time high heat phenomenon of the insulation layer when the cable is faulty,so as to study the effect of short time high heat on the microstructure and electrical properties of blended polypropylene insulation.Firstly,the sample was extracted from the cable insulation layer and subjected to short time high heat treatment.Secondly,the changes of physical and electrical properties of insulation samples before and after short time high heat treatment were compared.Finally,the microstructure changes in the insulation of mixed PP cable during short time high heat treatment were discussed and the influence mechanism of the microstructure changes on its electrical properties was analyzed.The results show that the continuity of the insulation phase deteriorates,the area of the elastomer phase decreases,and the number of interfacial layers increases after the cable insulation is subjected to short time high heat treatment.The molecular chain inside the insulation was broken,and the crystallinity decreased by 2.42%.Under industrial frequency,the insulation dielectric constant rises by 0.04,and the dielectric loss rises by 0.001 04.The number of deep traps inside the insulation increased,and the breakdown field strength decreased by 1.4%.

high voltage cablepolypropylene/elastomer blendshort time high heat treatmentmicrostructureelectrical property

曹建梅、杜宝帅、樊志彬、邢云琪、刘天垚

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国网山东省电力公司电力科学研究院,山东济南 250002

山东省智能电网技术创新中心,山东济南 250002

河北工业大学电气工程学院,天津 300131

电缆 聚丙烯/弹性体共混物 短时高热处理 微观结构 电气性能

国网山东省电力公司科技项目

2023A-144

2024

广东电力
广东电网公司电力科学研究院,广东省电机工程学会

广东电力

CSTPCD北大核心
影响因子:0.527
ISSN:1007-290X
年,卷(期):2024.37(9)
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