Sythesis and Non-isothermal Reaction Kinetics of a-SiWHMn and Tetrabutylammonium Charge-Transfer Complex
Charge-Transfer Complex ct-TBA4H2 [SiWIIO39Mn（H20）].xH20 were synthesized by solid phase in room tempreture. It was characterized by means of elementary analysis UV, TG-DT（2 The results indicate that heteropoly anion still remains its Keggin structure in supermolecular compounds. The non-isothermalkinetic data were analyzed with the Used Coats-Redfern method, and Doyle method. The mechanism function, kinetic parameters, apparent activation energy E and pre-exponential factor lnA of the thermal Decomposition were obtained.
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万方数据
维普
