首页|NCC/碱木质素硬质聚氨酯泡沫的制备

NCC/碱木质素硬质聚氨酯泡沫的制备

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首先以多亚甲基多苯基多异氰酸酯(PAPI)为原料,水为化学发泡剂,正戊烷为物理发泡剂,二甲基硅油为泡沫稳定剂,三乙烯二胺为催化剂,PAPI 与聚乙二醇(PEG)反应优化制备了硬质聚氨酯泡沫。制备优化工艺条件为异氰酸酯指数1.15,以20份(质量)PEG-400为标准,依次添加23份 PAPI,0.2份二甲基硅油、0.2份水、1.5份正戊烷和0.02份三乙烯二胺;在此基础上,添加0.4%(以 PEG-400计)纳米纤维素(NCC),碱木质素替代 PEG-400用量10%的情况下制备了 NCC/碱木质素硬质聚氨酯泡沫。
Preparation of NCC/Alkali Lignin Based Rigid Polyurethane Foam
Under the condition of polymethylene polyphenyl isocyanate (PAPI) as raw material, water as chemical foaming agent, n-pentane as physical blowing agent, dimethyl silicone as foam stabilizer, triethylenediamine as catalyst, the rigid polyurethane foam was prepared by PAPI reacting with polyethylene glycol(PEG). 20 parts (mass fraction) of PEG-400 as standard, optimal preparation conditions of polyurethane foam were isocyanate index 1.15, 23 parts of PAPI, 0.2 parts of dimethyl silicone, 0.2 parts of water, 1.5 parts of n-pentane, and 0.02 parts of triethylenediamine. On the basis of this condition, NCC/ alkali lignin based rigid polyurethane foam was prepared with addding 0.4 % NCC(calculated as PEG-400), adding 10 % alkali lignin in order to replace the dosage of PEG-400.

nanocrystalline cellulosealkali ligninpolyurethane foam

刘国超、刘志明

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东北林业大学 材料科学与工程学院 生物质材料科学与技术教育部重点实验室,黑龙江 哈尔滨 150040

纳米纤维素 碱木质素 聚氨酯泡沫

07041311401

2013

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2013.(7)
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