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污染物超临界水氧化技术防腐蚀研究进展

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超临界水氧化(SCWO)技术以超临界水(SCW)为介质,将有机污染物深度降解为CO2、H2O和N2以及无机盐等小分子化合物,具有反应快、降解彻底,无二次污染等明显优势,被誉为最有前途的污染物末端处理技术之一.然而,由于有机污染物氧化过程及中间产物复杂,使得设备工况环境苛刻且变化范围大,长时间运行极易遭受严重的腐蚀.为了提升污染物超临界水氧化系统的防腐蚀性能,使其实现规模化应用,科学家们通过耐腐蚀反应器研发,工程材料(金属、合金、陶瓷等)腐蚀过程和机理研究,卓有成效的工艺过程优化,强化了超临界水氧化系统中腐蚀发生、发展的认识,对防腐蚀技术的研发具有显著的促进作用,并己取得不少创新性成果.这些成果为开发新型防腐蚀超临界水氧化设备积累了丰富的基础数据,对其处理效果和效率提升,能量及运行成本核算等工业化设计提供了线索.
Progress in Anti-corrosion Investigation for the SCWO of Pollutants
Using supercritical water(SCW)as its reaction medium,supercritical water oxidation(SCWO)technology strongly oxidizes organic pollutants to small molecules such as CO2,H2O,N2,and inorganic salts,it is recognized as one of the most promising terminal routes for the pollutants due to its advantages of rapid oxidation,complete degradation,no secondary pollution,etc.However,complexity caused by the oxidation processes and intermediate products make the set-ups have harsh and widely-changed operational environments,as a result,they are prone to heavy corrosions as they long-termly operate.To improve the corrosion resistance of the SCWO system for its large scaled applications in the future,researchers deepen their knowledge of the corrosion occurrence and development in a SCWO system by the development of reactors,corrosion processes and mechanisms study of engineering materials(metal,alloy,ceramics,etc.),and effective optimization of techniques,resulting in great boosts of corrosion resistant techniques development and lots of novel research achievements.These results will not only accumulate basic data for the development of new anti-corrosive SCWO equipment,but also supply references for its treatment improvement and energy(cost)accounting in an industrial scale.

Supercritical water oxidation(SCWO)Supercritical water(SCW)corrosion

王光伟、陈鸿珍

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遵义师范学院,贵州遵义 563006

中国科学院重庆绿色智能技术研究院,重庆 400714

超临界水氧化 超临界水 腐蚀

贵州省自然科学基金重点项目

黔科合基础[2019]1461号

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(1)
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