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黄金湿法冶炼含氰废水深度处理工艺比选

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针对某黄金冶炼公司冶炼厂含氰废水,采用 Na2SO3/空气法、Na2S2O5/空气法、H2O2 氧化法、NaClO 氧化法四种工艺进行深度净化.试验确定Na2SO3/空气法处理的最佳工艺参数为:反应pH=9、反应时间25 min、Na2SO3药剂用量0.1 g/L;Na2S2O5/空气法处理的最佳工艺参数为:反应pH=10、反应时间30 min、Na2S2O5药剂用量0.1 g/L;H2O2氧化法处理,H2O2药剂用量0.15 g/L;NaClO氧化法处理,NaClO药剂用量0.2 g/L.通过对比分析以上4 种处理工艺的成本及优缺点,确定最佳处理工艺.本研究为含氰废水深度处理提供了技术支持.
Comparison and Selection of Advanced Treatment Processes for Cyanide Containing Wastewater from Gold Hydrometallurgy
Four treatment processes,namely Na2SO3/air method,Na2S2O5/air method,H2O2 oxidation method,and NaClO oxidation method,were used for deep purification of cyanide containing wastewater from a gold smelting company's smelting plant.The optimal process parameters for the Na2SO3/air method treatment were determined through experiments as follows:reaction pH=9,reaction time 25 minutes,and Na2SO3 dosage 0.1 g/L;The optimal process parameters for the Na2S2O5/air method treatment are:reaction pH=10,reaction time 30 minutes,and Na2S2O5 dosage 0.1 g/L;H2O2 oxidation method treatment,with a dosage of 0.15 g/L H2O2 agent;The NaClO oxidation method is used for treatment,with a NaClO reagent dosage of 0.2 g/L.By comparing and analyzing the costs,advantages,and disadvantages of the four treatment processes mentioned above,the optimal treatment process was determined.The study provides technical support for the advanced treatment of cyanide containing wastewater.

cyanide containing wastewaterNa2SO3/air methodNa2S2O5/air methodH2O2 oxidation methodchlor alkali oxidation method

刘锐利、赵次娴、戴镇璇、雷吟春、孟云、谭琴、廖圆、齐伟、王凯

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赛恩斯环保股份有限公司,湖南 长沙 410000

有色重金属污染治理装备湖南省工程实验室,湖南 长沙 410000

有色行业污染治理与装备工程技术研究中心,湖南 长沙 41000

含氰废水 Na2SO3/空气法 Na2S2O5/空气法 H2O2氧化法 氯碱氧化法

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(4)
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