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磷酸铁锂电池内置加热热失控研究

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锂离子电池的热失控触发主要有针刺,过充,加热,在电池内部局部添加加热膜,模拟电池内部短路引发的热失控;本文探究不同加热功率对磷酸铁锂电池热失控的影响,四组实验电池泄压阀未开启,均由密封材料失效导致加热线引出位置泄压排气,可提高密封材料耐温性加热改善。加热功率93 W依次增加至115 W,160 W,230 W,加热至热失控的时间由106 min依次缩短至70 min,42 min,23。37 min,并且随着加热功率,加热速率的增加,可降低电池热失控的触发温度;电池热失控后的最高温度与加热速率、加热能量相关,加热速率越快,电池增加的额外能量小,电池热失控后的最高温度降低。此外,加热膜尺寸一致,增加加热功率,加热至热失控所需的时间并不呈现线性关系。对测试后的样品采用CT进行结构与形貌表征;最后通过仿真技术,得出 115 W加热壳体温度变化曲线与115 W内置加热壳体温度曲线吻合,说明电池热性能参数正确。
Study on Thermal Runaway of Internal Heating of Lithium Iron Phosphate Battery
The thermal runaway triggers of lithium-ion batteries mainly include needling,overcharging,heating,and locally adding heating film inside the battery to simulate the thermal runaway caused by internal short circuit of the battery.This paper explores the influence of different heating power on the thermal runaway of lithium iron phosphate battery.The pressure relief valve of four experimental batteries is not opened,all of which are caused by the failure of sealing material,leading to pressure relief and exhaust at the heating wire outlet position,which can improve the temperature resistance of sealing material.The heating power increases from 93 W to 115 W,160 W and 230 W successively,and the heating time to thermal runaway is shortened from 106 min to 70 min,42 min and 23.37 min successively.In addition,with the increase of heating power and heating rate,the triggering temperature of the battery thermal runaway can be reduced.The maximum temperature of the battery after thermal runaway is related to the heating rate and heating energy.The faster the heating rate,the smaller the additional energy added by the battery,and the lower the maximum temperature after thermal runaway of the battery.In addition,the size of the heating film is consistent,and the time required to increase the heating power and heat to thermal runaway does not show a linear relationship.The structure and morphology of the tested samples were characterized by CT.Finally,through simulation technology,the temperature variation curve of 115 W heating shell is consistent with that of 115 W internal heating shell,indicating that the thermal performance parameters of the battery are correct.

lithium iron phosphatebuilt-in heatingthermal runawaytemperature

邱世涛、薛国正、李伟、钟志龙、张凯琦、肖鹏

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惠州亿纬锂能股份有限公司,广东 惠州 516000

磷酸铁锂 内置加热 热失控 温度

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(5)
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