首页|环境中持久性污染物短链氯化石蜡的光降解研究

环境中持久性污染物短链氯化石蜡的光降解研究

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近年来,短链氯化石蜡(SCCPs)成为彼受关注的持久性有机污染物,其对生物体具有蓄积和毒害效应,大量的含有 SCCPs的工业废水排放,对生态环境造成了潜在威胁。然而到目前为止,对于SCCPs在自然环境中的化学行为研究仍然很少,特别是对其在自然环境中的光催化降解研究仍然很少涉及。本文章探讨了我国SCCPs的使用和排放现状,分析了SCCPs在光照射条件下的催化降解行为研究现状,并通过实验模拟,研究了SCCPs在铁氧化物-草酸-紫外线催化体系中的降解行为,发现SCCPs在四种铁氧化物催化体系中均能被降达到接近79。9%,四种铁氧矿物的催化降解效率顺序为:α-Fe2O3>α-FeOOH>γ-Fe2O3>γ-FeOOH。
The Persistent Organic Pollutants of Short Chain Chlorinated Paraffins(SCCPs)Environmental Photocatalysis Study
As one of the persistent organic pollutants,short chain chlorinated paraffins(SCCPs)have aroused more and more attention in recent year.Because of the bio-accumulation and bio-toxic effect,Industrial wastewater discharge with high SCCPs concentration pose potential threat to the ecological environment.However,SCCPs environmental chemical behavior still lack of related studies so far,especially for the studies of SCCPs photocatalytic degradation process in the natural environment.In the present study,the domestic SCCPs emissions and photocatalytic degradation research status were analyzed.Simultaneously,through experimental simulation,SCCPs dechlorination behaviour in the iron oxide/oxalic acid photocatalytic system was investigated.The trial found that four kinds of iron oxides all showed degradation ability of SCCPs.The photocatalytic system with α-Fe2O3 have the maximum degradation rate up to 79.9%after 60 min uv irradiation.The rank of SCCPs degradation performance was α-Fe2O3>α-FeOOH>γ-Fe2O3>γ-FeOOH.

short chain chlorinated paraffins(SCCPs)iron oxidepersistent organic pollutant

陈雪泉

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广东环境保护工程职业学院,广东 佛山 528216

短链氯化石蜡(SCCPs) 铁氧化物 持久性污染物

广东省重点平台和重大科研项目

2018GkQNCX094

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(5)
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