广东化工2024,Vol.51Issue(6) :122-126.DOI:10.3969/j.issn.1007-1865.2024.06.036

离子色谱法和离子选择电极法对氟化氢溶液中的氟化物分析对比

Analysis and Comparison of Fluoride in Hydrogen Fluoride Solution by Ion Chromatography and Ion Selective Electrode

钟美芳 宋为 谭琴 高伟荣
广东化工2024,Vol.51Issue(6) :122-126.DOI:10.3969/j.issn.1007-1865.2024.06.036

离子色谱法和离子选择电极法对氟化氢溶液中的氟化物分析对比

Analysis and Comparison of Fluoride in Hydrogen Fluoride Solution by Ion Chromatography and Ion Selective Electrode

钟美芳 1宋为 1谭琴 1高伟荣2
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作者信息

  • 1. 湖南信泰环境服务有限公司,湖南长沙 410000;湖南有色行业重金属污染治理技术与装备工程技术中心,湖南长沙 410000
  • 2. 赛恩斯环保股份有限公司,湖南长沙 410000;有色重金属污染治理装备湖南省工程实验室,湖南长沙 410000
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摘要

氟化物指含负价氟的有机或无机化合物.与其他卤素类似,氟生成单负阴离子.无机氟化物的例子有氢氟酸(HF)、氟化钠(NaF)等.本文用离子选择电极法和离子色谱法分别分析含氢氟酸(HF)溶液中的氟化物.发现溶液含有氢氟酸(HF)时分析氟化物,分析结果与pH值形成干扰,pH值越低氟化物的结果越高,而采用氢氧化钠将溶液中和成碱性条件和用碳酸钠-碳酸氢钠淋洗液体系稀释样品时,干扰最小.而含氢氟酸(HF)溶液采用离子选择电极法分析时溶液pH值偏低,H+偏高,会氟化物的浓度偏高,而溶液pH值调至中性条件时干扰最小,结果最接近真值.

Abstract

Fluorides are organic or inorganic compounds containing negative valence fluorine.like other halogens,fluorine forms a mononegative anion.examples of inorganic fluorides are hydrofluoric acid(HF),sodium fluoride(NaF),etc.in this paper,the fluoride in hydrofluoric acid(HF)solution was analyzed by ion selective electrode method and ion chromatography.it was found that when the solution contained hydrofluoric acid(HF),the analysis result interfered with the pH value,and the lower the pH value,the higher the fluoride result.The interference was minimal when the solution was neutralized into an alkaline condition with sodium hydroxide and the sample was diluted with sodium bicarbonate-sodium bicarbonate eluent system.when the solution containing hydrofluoric acid(HF)is analyzed by ion selective electrode method,the pH value of the solution is low,and the H+is high,the concentration of fluoride is high,and the interference is minimum when the pH value of the solution is adjusted to the neutral condition,and the result is closest to the true value.

关键词

氟化氢/离子色谱法/离子选择电极法/氟化物

Key words

hydrogen fluoride/ion chromatography/ion selective electrode method/fluoride

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出版年

2024
广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
参考文献量5
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