首页|稠油热采用耐温高强度凝胶研制与性能评价

稠油热采用耐温高强度凝胶研制与性能评价

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针对目前多轮次稠油热采油藏普遍存在井间汽窜的问题,制备了含有丙烯酰胺(AM)、丙烯酸钠(AANa)、2-丙烯酰胺基-2-甲基丙磺酸钠(AMPSNa)结构单元的速溶耐盐聚合物。该聚合物与酚醛-有机铝复合交联剂发生交联反应,可形成耐温高强度凝胶,实现在稠油热采环境下对汽窜通道的长效封堵。主要利用流变学方法研究了不同交联剂体系对凝胶体系成胶的影响规律,并对现场适应性能进行了评价。结果表明,AM/AANa/AMPSNa聚合物在矿化度<25000 mg·L-1 的污水中30分钟完全溶解,无结块,具有良好的溶解性能;与酚醛-有机铝形成的耐温高强度凝胶体系可在油藏温度60~90℃下成胶,在温度150℃,矿化度<25000 mg·L-1 时,30天脱水率小于 10%。该凝胶在现场应用中污水适应性好,表现出优异的长期稳定性。
Preparation and Performance Evaluation of High Strength Gel with High Temperature Resistance for Heavy Oil Thermal Recovery
Aiming to solve the problems of inter-well steam channeling in multi-cycle heavy oil thermal recovery reservoirs,a salt-tolerant copolymer containing acrylamide(AM),sodium acrylate(AANa)and 2-acrylamide-2-methylpropanesulfonic sodium(AMPSNa)structural unit was prepared.The high strength gel with excellent temperature resistant performances was formed by crosslinking with phenolic and organoaluminum derivatives,which realized the long-term plugging of steam channeling channel for heavy oil thermal recovery.The effects of different crosslinking agent systems on gel formation were studied by rheological method,and the field adaptation performance was evaluated.The results show that AM/AANa/AMPSNa copolymer was completely dissolved in 30 min in sewage with salinity lower than 25000 mg·L-1,without agglomeration and had good solubility.The high strength gel system can be formed at reservoir temperature of 60~90℃,and the dehydration rate is less than 10%in 30 days when the temperature is 150℃and the salinity is less than 25000 mg·L-1.The gel has good adaptability to sewage in field application and shows excellent long-term stability.

polymergeltemperature-resistanthigh strengthplugging performance

胡晓娜、伊卓、刘希、李雅婧、张瑞琪、杨金彪

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中石化(北京)化工研究院有限公司,北京 100013

聚合物 凝胶 耐温 高强度 封堵

中国石化重点项目

420055-3

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(9)
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