首页|PEDOT类导电聚合物/碳纳米管/Pt复合材料的制备及其电催化

PEDOT类导电聚合物/碳纳米管/Pt复合材料的制备及其电催化

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本文以聚(3,4-乙撑二氧噻吩)/碳纳米管(PEDOT/CNT)复合材料为载体,将金属铂分散其表面,以提高铂催化剂的电催化性能以及抗中毒性和稳定性。分别采用红外光谱和扫描电子显微镜来对材料进行结构表征;通过循环伏安法(CV)与计时电流法(CA)对复合材料在甲醇和乙醇中的催化氧化性能进行探究。结果表明,与CNT/Pt催化剂相比,PEDOT/CNT/Pt催化剂具有更好的电催化甲醇、乙醇的能力,其电化学活性面积为 168。19 m2·g-1,与CNT/Pt催化剂(29。37 m2·g-1)相比,其电化学活性得到了极大的提高;其在甲醇、乙醇溶液中的质量活性电流密度分别为1134 mA·mg-1Pt、999 mA·mg-1,远高于CNT/Pt催化剂(281 mA·mg-1、235 mA·mg-1)。
Preparation and Electrocatalysis of PEDOT Conductive Polymer/Carbon Nanotubes/Pt Composite Materials
The precious metal platinum is dispersed on poly(3,4-ethylenedioxythiophene)/carbon nanotube(PEDOT/CNT)composite carriers in the article to improve the electrochemical performance,anti toxicity,and stability of platinum catalysts.The structure of the material was characterized using infrared spectroscopy and scanning electron microscopy,and the effect of polymer addition on the morphology of the composite was explored;Exploring the catalytic oxidation performance of composite materials in methanol and ethanol through cyclic voltammetry(CV)and chronoamperometry(CA).The results showed that compared with CNT/Pt catalyst,PEDOT/CNT/Pt catalyst has better electrocatalytic ability for methanol and ethanol,with an electrochemical active area of 168.19 m2·g-1.Compared with CNT/Pt catalyst(29.37 m2·g-1),its electrochemical activity was greatly improved;Its mass active current density in methanol and ethanol solutions is 1134 mA·mg-1 and 999 mA·mg-1,respectively,much higher than that of CNT/Pt catalysts(281 mA·mg-1 and 235 mA·mg-1).

PEDOTCNTelectrocatalytic performancemethanol fuel cell

黎之贤、肖培龙、任雯婧、马永志、吾热力森·阔马力别克、宋延艳、张玉、陈兆慧、如仙古丽·加玛力

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新疆大学,新疆 乌鲁木齐 830000

PEDOT CNT 电催化性能 甲醇燃料电池

新疆大学2022年国家级大学生创新训练计划项目

202210755034

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(12)