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废弃农用地膜与辣椒秸秆共混热解制备生物炭及其对含Cd(Ⅱ)废水的处理

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为了应对废弃农用地膜带来的环境问题,开发其合理的资源化利用途径,推进农业的绿色发展。本研究将废弃农用地膜与另一种农业废弃物辣椒秸秆进行共混热解制备生物炭,对所得生物炭的环境用途及理化特性进行探究。结果显示,废弃农用地膜与辣椒秸秆在700℃下制备的生物炭(M/C-700C)对Cd(Ⅱ)的吸附性能最佳,吸附量和去除率分别达19。55 mg·g-1和 97。44%。模型分析显示,M/C-700C对Cd(Ⅱ)的吸附过程属于均相单层、化学作用主导的反应。M/C-700C具有丰富的表面含氧官能团、C=C及矿物质,对Cd(Ⅱ)的高效吸附扮演着重要作用。本研究表明,共混热解可开发作为废弃农用地膜资源化利用的可行方法。
Preparation of Biochar from Co-pyrolysis of Waste Mulching Film and Chili Straw and Its Treatment Capability toward Cd(Ⅱ)-containing Wastewater
To address the environmental issues caused by waste mulching film,develop reasonable ways to utilise its resources,and promote the green development of agriculture,this study focused on the co-pyrolysis of waste mulching film and chili straw,one of the agricultural wastes,to produce biochar.The study investigated the environmental applications and physicochemical properties of the biochar obtained.The results indicate that biochar prepared by co-pyrolysis of waste mulching film and chili straw at 700℃(M/C-700C)exhibits optimal adsorption performance for Cd(Ⅱ),with the adsorption capacity and the removal efficiency reaching 19.55 mg·g-1 and 97.44%respectively.Model analysis suggests that the adsorption process of M/C-700C for Cd(Ⅱ)belongs to a homogeneous monolayer,and chemically dominant process.M/C-700C is rich in surface oxygen functional groups,C=C bonds,and minerals,acting as efficient adsorption sites for Cd(Ⅱ).This study demonstrates that co-pyrolysis can be developed as an effective method for the resource utilisation of waste mulching film.

mulching filmchili strawco-pyrolysisbiocharadsorptionCd(Ⅱ)

贾田、吴道明、蔡景行、蒋科

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贵阳市乡村振兴服务中心,贵州 贵阳 550081

贵州民族大学贵州省高等学校塑料应用绿色低碳技术工程研究中心,贵州 贵阳 550025

地膜 辣椒秸秆 共混热解 生物炭 吸附 Cd(Ⅱ)

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(13)