首页|气相色谱单柱法测定新会柑果皮中三唑磷农药残留的不确定度评定

气相色谱单柱法测定新会柑果皮中三唑磷农药残留的不确定度评定

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目的:评定气相色谱单柱法测定新会柑果皮中三唑磷农药残留的不确定度.方法:建立计算模型,分析和计算农药残留测量结果的不确定度分量,得出农药残留量的不确定度.结果:当新会柑果皮三唑磷残留量为1.25 mg/kg,其扩展不确定度为0.52 mg/kg(置信因子k=2).结论:标准系列曲线拟合过程是影响该方法不确定度的主要因素,其次样品的前处理对不确定度产生的影响也较大.因此,在新会柑果皮的三唑磷农药残留测定中,应从这两个方面加以重视,以提高准确性.
Uncertainty Evaluation for Determination of Triazophos Residues in Xinhui Citrus Peel by Gas Chromatography Single-column Method
Objective:To evaluate the uncertainty of Gas chromatography in the determination of triazophos pesticide residues in citrus peel of Xinhui District.Methods:The uncertainty components of pesticide residues were analyzed and calculated by establishing a calculation model,and the uncertainty of pesticide residues was obtained.Results:When the residue of triazophos in Xinhui District peel was 1.25 mg/kg,the expanded uncertainty was 0.52 mg/kg(confidence factor k=2).Conclusion:The fitting process of standard series curve is the main factor affecting the uncertainty of this method,and the pretreatment of samples has a greater impact on the uncertainty.Therefore,the determination of triazophos pesticide residues in Xinhui District orange peel should pay attention to these two aspects in order to improve the accuracy.

gas chromatographyXinhui citrus peelpesticide residueuncertainty

熊文明、周敏瑜、皮小弟

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广东江门中医药职业学院,广东 江门 529000

气相色谱法 新会柑果皮 农药残留 不确定度

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(13)