首页|便携式气相色谱-质谱法测定环境空气中挥发性有机物的方法验证

便携式气相色谱-质谱法测定环境空气中挥发性有机物的方法验证

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本文建立了环境空气中挥发性有机物的便携式气质联用分析方法,规范了实验室检测步骤.进行了 52 种挥发性有机物的高/低浓度曲线分析,检出限和测定下限,精密度和正确度的分析.结果表明:52 种化合物的高/低浓度校准曲线的相关系数均大于 0.990,线性关系良好;检出限范围为0.4 μg/m3~5.0 μg/m3,测定下限的范围为 1.7 μg/m3~20.0 μg/m3,不大于标准中检出限和测定下限;相对标准偏差均小于25%,加标回收率范围均在70%~130%之内,具有良好的精密度和准确度.该方法适用于环境空气中挥发性有机物的测定.
Determination of Volatile Organic Compounds in Ambient Air by Portable Gas Chromatography-Mass Spectrometry
In this paper,a portable gas chromatography-mass spectrometry method for volatile organic compounds in ambient air was established and the laboratory detection procedures were standardized.The analysis of high/low concentration curve,detection limit and determination limit,precision and accuracy of 52 kinds of volatile organic compounds was carried out.The results showed that the correlation coefficients of the high/low concentration calibration curves for 52 compounds were all greater than 0.990,indicating a good linear relationship.The range of detection limit was 0.4 μg/m3~5.0 μg/m3,and the range of determination limit was 1.7 μg/m3~20.0 μg/m3,which were not greater than the detection limit and determination lower limit in the standard.The relative standard deviation was less than 25%,and the recovery range of standard addition was within 70%~130%,indicating good precision and accuracy.This method is suitable for the determination of volatile organic compounds in ambient air.

portable gas chromatography-mass spectrometryvolatile organic compoundsdetection limitprecisionaccuracy

张峰

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河南省新乡生态环境监测中心,河南 新乡 453000

便携式气相色谱-质谱法 挥发性有机物 检出限 精密度 正确度

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(13)