首页|氧化锌共掺杂薄膜的光电性能研究

氧化锌共掺杂薄膜的光电性能研究

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为研究不同掺杂氧化锌靶材制备薄膜的光电性能,采用了AZO和AGZO靶材制备薄膜样品,研究不同靶基距下制备AZO薄膜的均匀性,同时研究了不同溅射工艺参数下的AZO、AGZO薄膜的光电性能,此外,通过对比分析AZO、AGZO薄膜之间的性能差异,探究靶材组分改进对薄膜性能的影响和机理。实验结果表明,靶基距为 9 cm 沉积薄膜的厚度均匀性较好;在纯氩条件制备的AZO和AGZO薄膜的方阻最低,此外,AZO和AGZO薄膜在300 nm~1300 nm的较宽区域均展现了良好的光学透射性能,在 200℃/0%O2 的参数条件下,AZO和AGZO薄膜的电阻率在 10-3 Ω·cm量级,载流子浓度在 1020 cm-3量级,其中III族元素的掺杂量增大的AGZO(2。6 wt%Al2O3+Ga2O3)在最佳工艺参数条件制备的薄膜的光电性能更为优越。
Study on Photoelectric Properties of Zinc Oxide Co-doped Thin Films
In order to study the photoelectric properties of films prepared by different doped zinc oxide targets,AZO and AGZO targets were used to prepare film samples,and the homogeneity of AZO films prepared by different target base distances was studied.Meanwhile,the photoelectric properties of AZO and AGZO films under different sputtering process parameters were studied.Through comparative analysis of the properties of AZO and AGZO films,the influence and mechanism of improving the composition of the target material on the properties of the films were explored.The experimental results show that the thickness uniformity of the film is better when the target base distance is 9 cm.The square resistance of AZO and AGZO films prepared in pure argon is the lowest.In addition,both AZO and AGZO films exhibit good optical transmission properties in a wide region ranging from 300 nm to 1300 nm.At 200℃/0%O2,the resistivity of AZO and AGZO films is in the order of 10-3 Ω·cm and the carrier concentration is in the order of 1020 cm-3.The photoelectronic properties of the films prepared by AGZO(2.6 wt%Al2O3+Ga2O3)with the increase of the doping amount of Group III elements are better under the optimum process parameters.

magnetron sputteringtarget substrate distancethin filmAZOAGZOphotoelectric performance

李粮任、朱刘

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广东先导稀材股份有限公司,广东 清远 511517

国家稀散金属工程技术研究中心,广东 清远 511517

磁控溅射 靶基距 薄膜 铝掺杂氧化锌 铝镓掺杂氧化锌 光电性能

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(14)