首页|印染废水中溶解性有机质在非均相芬顿工艺下的转化与去除研究

印染废水中溶解性有机质在非均相芬顿工艺下的转化与去除研究

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随着工业化进程的加快,工业生产制造导致越来越多的污染物排放,造成了水体的严重污染.纺织行业所排放的废水成分复杂且难处理,而高级氧化工艺(AOPs)是解决这种难处理的工业废水的一种有效措施.本研究针对国内某工业园区一家印染厂采集的印染废水,开展非均相芬顿降解实验,采用傅里叶变换离子回旋共振质谱对其组分进行检测与识别.探究印染废水中溶解性有机质(DOM)的组成特征及其在非均相芬顿实验中的转化与去除过程.结论表明印染废水中DOM以木质素和脂肪族化合物为主,非均相芬顿工艺反应30分钟后,大分子有机物降解为小分子物质,DOM的整体质荷比下降.反应4 小时后的降解效果与 30分钟相差不大,非均相芬顿工艺降解后DOM组分的O/C更高,富含更多含N有机物.
Study on the Transformation and Removal of Dissolved Organic Matter in Printing and Dyeing Wastewater under Heterogeneous Fenton Process
With the acceleration of industrialization,industrial production and manufacturing have led to more and more pollutant emissions,causing serious pollution of water bodies.The composition of wastewater discharged by the textile industry is complex and difficult to treat,and advanced oxidation processes(AOPs)are an effective measure to solve this difficult industrial wastewater.This study conducted heterogeneous Fenton degradation experiments on printing and dyeing wastewater collected from a printing and dyeing factory in a certain industrial park in China.The components were detected and identified using Fourier transform ion cyclotron resonance mass spectrometry.Exploring the composition characteristics of dissolved organic matter(DOM)in printing and dyeing wastewater and its transformation and removal processes in heterogeneous Fenton experiments.The conclusion indicates that lignin and aliphatic compounds are the main components of DOM in printing and dyeing wastewater.After 30 minutes of heterogeneous Fenton process reaction,macromolecular organic matter is degraded into small molecule substances,and the overall mass to charge ratio of DOM decreases.The degradation effect after 4 hours of reaction is not significantly different from that after 30 minutes.After heterogeneous Fenton process degradation,the O/C of the DOM component is higher,and it is rich in more N-containing organic compounds.

printing and dyeing wastewaterdissolved organic matteradvanced oxidationnon homogeneous Fenton processhigh resolution mass spectrometry

谢健、张娟、董鑫淼、顾清清、张烨铠

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河北工程大学,河北 邯郸 056038

印染废水 溶解性有机质 高级氧化 非均相芬顿工艺 高分辨率质谱

2024

广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
年,卷(期):2024.51(14)