广东化工2024,Vol.51Issue(15) :7-9.DOI:10.3969/j.issn.1007-1865.2024.015.003

氯化铵浸取电石渣中钙离子的研究

Study on Extraction of Calcium Ions from Calcium Carbide Slag by Ammonium Chloride Leaching

陈宁 郑凤 左周
广东化工2024,Vol.51Issue(15) :7-9.DOI:10.3969/j.issn.1007-1865.2024.015.003

氯化铵浸取电石渣中钙离子的研究

Study on Extraction of Calcium Ions from Calcium Carbide Slag by Ammonium Chloride Leaching

陈宁 1郑凤 1左周1
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作者信息

  • 1. 绵阳师范学院,四川绵阳 621000
  • 折叠

摘要

电石渣是工业生产乙炔气过程中电石水解后产生的废渣,主要成分是Ca(OH)2.文章以氯化铵为浸取剂,提取电石渣中的钙离子,以达到提纯钙和资源化利用的目的.实验探究了不同用水量、氯化铵用量、反应温度及反应时间下Ca2+浸取率,探讨了氯化铵浸取机理,同时对浸取液和滤渣的成分进行了详细分析.结果表明,当浸取温度25℃,浸取时间40 min,电石渣∶氯化铵∶用水量=5∶6∶35时,电石渣中的Ca2+浸取率最高,为76.58%.经氯化铵浸取,电石渣中的Mg、Al、Fe、C等杂质被去除,Ca2+纯度达到98%,滤渣中的主要成分为炭黑、碳酸钙、水铝钙石、钙矾石.

Abstract

Calcium carbide slag is a waste residue generated after the hydrolysis of calcium carbide in the industrial production of acetylene gas,mainly composed of Ca(OH)2.In order to achieve the purpose of purifying calcium and resource utilization,the article uses ammonium chloride solution as a leaching agent to extract calcium ions from calcium carbide slag.The leaching rate of Ca2+under different water usage,ammonium chloride dosage,reaction temperature and reaction time were investigated through experiments,and a detailed analysis of the leaching solution and filter residue compositions were conducted.The results shows that the Ca2+leaching rate can be reach to the highest at 76.58%,when the reaction temperature is 25 ℃,reaction time is 40 min,and the ratio of carbide slag:Ammonium chloride:water consumption is 5∶6∶35.After leached with ammonium chloride,impurities such as Mg,Al,Fe and C in the carbide slag were removed,and the purity of Ca2+reached to 98%.The main components of the filter slag are carbon powder,calcium carbonate,hydrocalumite and ettringite.

关键词

氯化铵/电石渣/浸取率/浸取液/滤渣

Key words

ammonium chloride/calcium carbide slag/leaching rate/leaching solution/filter residue

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出版年

2024
广东化工
广东省石油化工研究院

广东化工

影响因子:0.288
ISSN:1007-1865
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